936030

Sodium triflate

≥99.5% trace metals basis, anhydrous, battery grade

• Synonyme(s) : Sodium trifluoromethanesulfonate, NaTfO, Sodium triflate, Trifluoromethanesulfonic acid sodium salt
• Formule linéaire : CF₃SO₃Na
• Numéro CAS: 2926-30-9
• Poids moléculaire : 172.06
• UNSPSC Code: 12352104
• Beilstein/REAXYS Number: 3728797
• MDL number: MFCD00061607
• NACRES: NA.21

Propriétés

• grade: battery grade
• Quality Segment: 100
• assay: ≥99.5% trace metals basis
• form: powder or crystals
• sustainability: Sustainability features
• impurities: ≤5000 ppm trace metals
• mp: 253-255 °C, 253-255 °C (lit.)
• application(s): battery manufacturing; battery precursors
• SMILES string: [Na+].[O-]S(=O)(=O)C(F)(F)F
• InChI: 1S/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
• InChI key: XGPOMXSYOKFBHS-UHFFFAOYSA-M

Description

General description

Sodium trifluoromethanesulfonate, or sodium triflate (NaTfO), is a white, crystalline salt. It is hygroscopic and deliquescent. NaTfO is soluble in water, acetonitrile, some carbonates (including dimethyl carbonate and propylene carbonate, but insoluble in diethyl carbonate), glymes (including monoglyme, diglyme, and triglyme), dimethoxyethane, and most polar organic solvents. It is thermally stable and melts at 253 - 255 °C. NaTfO can be prepared by reaction of sodium sulfate and barium trifluoromethanesulfonate. Alternatively, it can be prepared by reaction between sodium dithionite and bromotrifluoromethane.

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Application

Our sodium trifluoromethanesulfonate offers the high purity and low water content ideal for use as an electrolytic salt in sodium-ion batteries. NaTfO is compatible with many cathode and anode materials used in sodium-ion batteries, including sodium metal anodes used in sodium metal batteries Additionally, NaTfO dissolved in diglyme has enabled the use of graphite in reversible sodium-ion batteries When electrolytes comprised of NaTfO dissolved in diglyme, tetraglyme, or 1,2-dimethoxyethane are used with graphite anodes, solvated sodium co-intercalates along with its anion facilitating fast kinetics and high charge rates Researchers have also found that sodium trifluoromethanesulfonate performs well with layered chalcogenides like FeS₂ and CoSe₂ when other electrolytes perform poorly. Lastly, high-purity NaTfO dissolved in diglyme and 1,3-dioxolane has shown promise as an electrolyte in sodium-oxygen batteries form a thin stable passivation film on the alkali metal anode.

Informations sur la sécurité

• Pictogrammes: GHS07
• Mot-clé: Warning
• Codes de danger: H315,H319,H335
• Mentions de précaution: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Classe de stockage: 11 - Combustible Solids
• Que se passe-t-il ?: WGK 2
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable