904694

Ir(p-CF₃-ppy)₃

≥95%, powder or crystals

• Synonym(s): Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium
• Empirical Formula (Hill Notation): C₃₆H₂₁F₉IrN₃
• CAS Number: 500295-52-3
• Molecular Weight: 858.77
• MDL number: MFCD31657272
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• Product Name: Ir(p-CF₃-ppy)₃, ≥95%
• assay: ≥95%
• form: powder or crystals
• reaction suitability: core: iridium, reagent type: catalyst; reaction type: Photocatalysis
• mp: >300 °C
• photocatalyst activation: 465 nm
• SMILES string: [Ir]741([NH]8=C(c9c7cc(cc9)C(F)(F)F)C=CC=C8)([NH]5=C(c6c4cc(cc6)C(F)(F)F)C=CC=C5)[NH]2=C(c3c1cc(cc3)C(F)(F)F)C=CC=C2
• InChI: 1S/3C12H7F3N.Ir/c3*13-12(14,15)10-6-4-9(5-7-10)11-3-1-2-8-16-11;/h3*1-4,6-8H;
• InChI key: ZLVNAIXHGHEODI-UHFFFAOYSA-N

Description

Application

This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Photocatalytic C–F alkylation; facile access to multifluorinated arenes

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable