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908568

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6

≥95%, powder or crystals

Synonym(s):

[5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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Size/SKUAvailabilityPrice
100 mg
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£173.00
£129.75
500 mg
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£553.00

About This Item

Empirical Formula (Hill Notation):
C36H16F22IrN4P
CAS Number:
1973375-72-2
Molecular Weight:
1145.69
MDL number:
MFCD31707657
UNSPSC Code:
12352101
NACRES:
NA.22

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Product Name

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

photocatalyst activation

460 nm

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H5F5N.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-7(2,3,4,5)6;/h1-6H;2*1-2,4-6H;;/q;;;-1;+1

InChI key

QEXYETWHTSSWGM-UHFFFAOYSA-N

Application

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation

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[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%

Sigma-Aldrich

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

(Ir[Me(Me)ppy]2(dtbpy))PF6

Sigma-Aldrich

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

Ir(dFppy)3

Sigma-Aldrich

900540

Ir(dFppy)3

description

≥95%

description

≥95%

description

-

description

-

assay

≥95%

assay

≥95%

assay

-

assay

-

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reagent type: catalyst
core: iridium
reaction type: Photocatalysis

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

reagent type: catalyst, core: iridium, reaction type: Photocatalysis

form

powder or crystals

form

powder or crystals

form

powder

form

powder or crystals

mp

>300 °C

mp

-

mp

-

mp

401 °C

photocatalyst activation

460 nm

photocatalyst activation

450 nm

photocatalyst activation

465 nm

photocatalyst activation

450 nm

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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