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908703

Sigma-Aldrich

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%, powder or crystals

Synonym(s):

[(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

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100 MG
£139.00
500 MG
£455.00

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100 MG
£139.00
500 MG
£455.00

About This Item

Empirical Formula (Hill Notation):
C42H42F8IrN4P
CAS Number:
808142-88-3
Molecular Weight:
977.99
MDL number:
MFCD31707653
UNSPSC Code:
12352101
NACRES:
NA.22

£139.00

Please contact Customer Service for Availability
Request a Bulk Order

Product Name

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

Assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

450 nm

InChI key

SNWREQGMGVVZPS-UHFFFAOYSA-N

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This Item
908568905917901409
[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

(Ir[Me(Me)ppy]2(dtbpy))PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

assay

≥95%

assay

≥95%

assay

-

assay

-

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

-

reaction suitability

-

form

powder or crystals

form

powder or crystals

form

powder

form

solid

photocatalyst activation

450 nm

photocatalyst activation

460 nm

photocatalyst activation

465 nm

photocatalyst activation

450 nm

Application

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3419
MKCT0580

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