Skip to Content
Merck

Skip To

242381

Benzoic acid

ACS reagent grade, ≥99.5%, crystalline

Synonym(s):

Benzenecarboxylic acid, Carboxybenzene

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Pack SizeSKUAvailabilityPrice
25 g
Please contact Customer Service for Availability
£17.00
100 g
Please contact Customer Service for Availability
£21.20
500 g
Please contact Customer Service for Availability
£58.70
3 kg
Please contact Customer Service for Availability
£287.00

About This Item

Linear Formula:
C6H5COOH
CAS Number:
Molecular Weight:
122.12
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39023903
UNSPSC Code:
12352100
EC Number:
200-618-2
MDL number:
Beilstein/REAXYS Number:
636131
Assay:
≥99.5%
Form:
crystalline

£17.00


Please contact Customer Service for Availability

Request a Bulk Order
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Product Name

Benzoic acid, ACS reagent, ≥99.5%

grade

ACS reagent

Quality Level

vapor density

4.21 (vs air)

vapor pressure

10 mmHg ( 132 °C)

assay

≥99.5%

form

crystalline

autoignition temp.

1061 °F

packaging

poly bottle of 25, 100, 500 g, poly drum of 3 kg

impurities

MnO4- reducers, passes test, ≤0.002% S compounds, ≤0.005% CH3OH insol.

ign. residue

≤0.005%

bp

249 °C (lit.)

mp

121-125 °C (lit.)

solubility

water: soluble (2.9 g/l at 25 °C)

anion traces

chloride (Cl-): ≤0.005%

cation traces

heavy metals (as Pb): ≤5 ppm

functional group

carboxylic acid, phenyl

SMILES string

OC(=O)c1ccccc1

InChI

1S/C7H6O2/c8-7(9)6-4-2-1-3-5-6/h1-5H,(H,8,9)

InChI key

WPYMKLBDIGXBTP-UHFFFAOYSA-N

General description

Benzoic acid is an organic aromatic monocarboxylic acid. It can be synthesized by the cobalt or manganese catalyzed atmospheric oxidation of toluene. Recently, benzoic acid has been prepared from toluene by employing TiO2 nanotubes electrode.
Benzoic acid reacts with hydrogenating reagents to afford hexahydrobenzoic acid. The thermal decomposition of the product in the presence of lime or alkali produces benzene and carbon dioxide.

Application

Benzoic acid has been used in the preparation of vials for the HPLC analysis of various polyamines in biological fluids, tissues and isolated/cultured cells.[1]
It may be employed as an intermediate in the synthesis of the following:
  • paints
  • pigments
  • varnish
  • wetting agents
  • aroma compounds
  • benzoyl chloride
  • benzotrichloride
It may also be used to investigate the mechanism of complex addition reaction of hydroxyl radicals with various aromatic compounds.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
109479427608W213128
assay

≥99.5%

assay

99%

assay

≥99%

assay

≥99.5%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

300, 400

solubility

water: soluble (2.9 g/l at 25 °C)

solubility

water: soluble 2.9 g/L at 25 °C

solubility

alcohol: soluble(lit.), benzene: soluble(lit.), chloroform: soluble(lit.)

solubility

water: 2.9 g/L at 25 °C

bp

249 °C (lit.)

bp

249 °C (lit.)

bp

249 °C (lit.)

bp

132-133 °C/10 mmHg, 249 °C (lit.)

form

crystalline

form

crystalline

form

crystalline

form

powder

mp

121-125 °C (lit.)

mp

121-125 °C (lit.)

mp

121-125 °C (lit.)

mp

121-125 °C (lit.)


Still not finding the right product?

Explore all of our products under Benzoic acid


pictograms

Health hazardCorrosion

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT RE 1 Inhalation

target_organs

Lungs

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library


Articles

Acid and base chart lists the strength of acids and bases (strongest to weakest) in order. Simple to use laboratory reference chart for scientists, researchers and lab technicians.


Zhaolai Dai et al.
Amino acids, 46(6), 1557-1564 (2014-03-19)
Polyamines (putrescine, spermine and spermidine) play a crucial role in the regulation of cell growth, differentiation, death and function. Accurate measurement of these substances is essential for studying their metabolism in cells. This protocol describes detailed procedures for sample preparation
Hydroxylation by electrochemically generated OH. radicals. Mono-and polyhydroxylation of benzoic acid: products and isomer distribution.
Oturan MA and Pinson J.
The Journal of Physical Chemistry, 99(38), 13948-13954 (1995)
Eagleson M.
Concise Encyclopedia Chemistry, 122-122 (1994)



Global Trade Item Number

SKUGTIN
242381-3KG04061825589350
242381-25G04061835554706
242381-100G04061825589343
242381-500G04061835554713

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hello, The Benzoic acid ACS reagents CAS number 65-85-0 can be considered as a primary standard? Thanks

    1 answer
    1. This product is not a primary standard.

      Helpful?

Reviews

No rating value

Active Filters