This product is packaged using the Sure/Seal™system which is used for anhydrous and air sensitive solvents. The bottle was sealed under an inert atmosphere.
517127
Dimethyl carbonate
anhydrous, ≥99%
Synonym(s):
DMC, Carbonic acid dimethyl ester
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| Size/SKU | Availability | Price |
|---|---|---|
100 mL | Please contact Customer Service for Availability | £46.10 |
1 L | Please contact Customer Service for Availability | £143.00 |
2 L | Please contact Customer Service for Availability | £226.00 |
About This Item
Linear Formula:
(CH3O)2CO
CAS Number:
Molecular Weight:
90.08
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
210-478-4
Beilstein/REAXYS Number:
635821
MDL number:
Assay:
≥99%
Grade:
anhydrous
Bp:
90 °C (lit.)
Vapor pressure:
18 mmHg ( 21.1 °C)
grade
anhydrous
Quality Segment
vapor density
3.1 (vs air)
vapor pressure
18 mmHg ( 21.1 °C)
assay
≥99%
expl. lim.
4.22-12.87 % (lit.)
greener alternative product characteristics
Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
impurities
<0.002% water, <0.005% water (100mL pkg)
color
APHA: <50
refractive index
n20/D 1.368 (lit.)
bp
90 °C (lit.)
mp
2-4 °C (lit.)
density
1.069 g/mL at 25 °C (lit.)
greener alternative category
SMILES string
O=C(OC)OC
InChI
1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
InChI key
IEJIGPNLZYLLBP-UHFFFAOYSA-N
General description
Dimethyl carbonate (DMC) is a versatile, non-toxic, biodegradable reagent with tunable chemical reactivity. It serves as a green alternative to dimethyl sulfate or methyl halides and phosgene for methylation and carboxylation reactions.[1] DMC can be prepared by the base-catalyzed reaction between carbon dioxide and methanol.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a Greener alternative to conventional solvents and chemicals. Click here for more information.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a Greener alternative to conventional solvents and chemicals. Click here for more information.
Application
Dimethyl carbonate has been used to dissolve poly (lactic-co-glycolic acid) (PLGA) to form PLGA-coated bioactive glass-ceramic scaffolds.
Features and Benefits
Greener solvent
1 of 1
This Item | |||
|---|---|---|---|
| Quality Level 100 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| assay ≥99% | assay 99% | assay ≥99.0% (GC) | assay ≥99.0% (GC) |
| grade anhydrous | grade - | grade synthesis grade | grade analytical standard |
| vapor pressure 18 mmHg ( 21.1 °C) | vapor pressure 18 mmHg ( 21.1 °C) | vapor pressure 53 hPa ( 20 °C) | vapor pressure 18 mmHg ( 21.1 °C) |
| vapor density 3.1 (vs air) | vapor density 3.1 (vs air) | vapor density - | vapor density 3.1 (vs air) |
| refractive index n20/D 1.368 (lit.) | refractive index n20/D 1.368 (lit.) | refractive index - | refractive index n20/D 1.368 (lit.), n20/D 1.369 |
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signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Could you confirm whether the bottle was sealed under argon, nitrogen, or vacuum?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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What is the difference between anhydrous and battery grade? Can we use this in lithium and sodium ion batteries as a solvent for electrolyte?
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The difference between anhydrous and battery grade dimethyl carbonate (DMC) lies in their purity and specific testing. Battery grade DMC has an acid content test, while anhydrous grade does not. There is no indication that anhydrous grade can't be used as a solvent for electrolytes in lithium and sodium ion batteries; however, battery grade is more recommended if available.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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