If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 g | Please contact Customer Service for Availability | £24.10 | |
| 100 g | Please contact Customer Service for Availability | £42.50 | |
| 250 g | Please contact Customer Service for Availability | £64.60 | |
| 500 g | Please contact Customer Service for Availability | £98.50 | |
| 2.5 kg | Please contact Customer Service for Availability | £306.00 | |
| 12 kg | Please contact Customer Service for Availability | £1,160.00 |
About This Item
grade
ACS reagent
Quality Level
vapor pressure
7.3 mmHg ( 25 °C)
assay
≥98.0%, 98.0-102.0% (ACS specification)
form
crystals
reaction suitability
reaction type: click chemistry, reagent type: catalyst
core: copper
pH
3.5-4.5 (20 °C, 50 g/L)
mp
110 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤0.001%
cation traces
Ca: ≤0.005%, Fe: ≤0.003%, K: ≤0.01%, Na: ≤0.02%, Ni: ≤0.005%
SMILES string
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
General description
Application
- In acetylation of alcohols and phenols in the presence of acetic anhydride.
- To synthesize various ynamides via intramolecular coupling of amides with alkynyl bromides.
It can also be used as a template in the synthesis of copper(II) ion-imprinted polymers using vinylpyridine and methacrylic acid as functional monomers. This polymer is used to quantify Cu2+ ion by using flame atomic absorption spectroscopy.
Features and Benefits
1 of 1
This Item | |||
|---|---|---|---|
| form crystals | form powder or crystals | form crystals and lumps | form fine powder |
| assay ≥98.0%, 98.0-102.0% (ACS specification) | assay ≥98.0% | assay 99.999% trace metals basis | assay - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 500 |
| grade ACS reagent | grade - | grade - | grade - |
| pH 3.5-4.5 (20 °C, 50 g/L) | pH 3.7-4.5 (25 °C, 50 g/L) | pH - | pH 3.5-4.5 (20 °C, 50 g/L in H2O) |
| mp 110 °C (dec.) (lit.) | mp 110 °C (dec.) (lit.) | mp 110 °C (dec.) (lit.) | mp 147 °C |
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Storage Class
11 - Combustible Solids
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 209198-2.5KG | 04061835346585 |
| 209198-100G | 04061837768453 |
| 209198-5G | 04061837768484 |
| 209198-25KG | 04061833636473 |
| 209198-12KG | 04061838770592 |
| 209198-500G | 04061837768477 |
| 209198-250G | 04061837768460 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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