Merck
所有图片(1)

19997

Sigma-Aldrich

叔丁基过氧化氢 溶液

packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4Å)

别名:
1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP
线性分子式:
(CH3)3COOH
CAS号:
分子量:
90.12
Beilstein:
1098280
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

质量水平

100

测定

52.9-66.8% (iodometric)

形式

liquid

质量

packed in FEP bottles

reaction suitability

reagent type: oxidant

浓度

~5.5 M in decane (over molecular sieve 4Å)

折射率

n20/D 1.403

密度

0.83 g/mL at 20 °C

储存温度

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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应用

用于燃料的氧化脱硫以及作为苯乙烯环氧化的氧化剂。

包装

25, 100 mL in PFA/FEP bottle

其他说明

用于Sharpless环氧化的安全稳定的氧化剂

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

闪点(F)

109.4 °F - closed cup

闪点(C)

43 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

分析证书

请输入批号搜索分析证书(COA)。

原产地证书 (CofO)

请输入批号搜索原产地证书(COO)。

更多文件

Quotes and Ordering

Controlled synthesis of a- and c-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on a-Fe2O3 catalyzed styrene epoxidation.
Bepari RA,et al.
Journal of Saudi Chemical Society (2014)
Oxidative desulfurization of fuel oil. Part I. Oxidation of dibenzothiphenes using tert-butyl hydroperoxide
Wang D,et al.
Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
T. Katsuki et al.
Org. React., 48, 1-1 (1996)
Qiong Tang et al.
Ultrasonics sonochemistry, 20(5), 1168-1175 (2013-03-30)
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The

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