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品質等級
化驗
99.99% trace metals basis
形狀
solid
反應適用性
core: thallium
reagent type: catalyst
mp
632 °C (lit.)
密度
6.77 g/mL at 25 °C (lit.)
SMILES 字串
[Tl+].[Tl+].[O-]S([O-])(=O)=O
InChI
1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2
InChI 密鑰
YTQVHRVITVLIRD-UHFFFAOYSA-L
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一般說明
Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.
應用
Thallium(I)sulfate is also utilized in:
- the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
- inthe preparation of thallium borate species such as TlBPH43
訊號詞
Danger
危險分類
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
J P Keogh et al.
Journal of toxicology and environmental health, 43(3), 351-359 (1994-11-01)
Cytotoxicities of metal salts were determined in the intestinal epithelial cell line I-407 in microwell culture plates over 48 h using the widely utilized and accepted neutral red uptake procedure. Rank order cytotoxicities induced by the metal salts (in terms
Changes in adenosine triphosphate (ATP) concentration and its activity in murine tissue after thallium administration.
M Yoshida et al.
Bulletin of environmental contamination and toxicology, 59(2), 268-273 (1997-08-01)
L Migliore et al.
Environmental and molecular mutagenesis, 34(4), 279-284 (2000-01-05)
The capability of some metal compounds for inducing micronuclei (MN) in human lymphocytes was studied. In this investigation, Al (III), Cd (II), Hg (II), Sb (V), Te (VI), and Tl (I) salts were considered. The FISH (fluorescence in situ hybridization)
D Appenroth et al.
Toxicology letters, 122(3), 255-265 (2001-08-08)
Antioxidants of the vitamin E family have protective effects against metal toxicity. We examined the protective effect of racemic LLU-alpha [2,7,8-trimethyl-2-(carboxyethyl)-6-hydroxychroman] a metabolite of gamma-tocopherol, in comparison to the effect of alpha- and gamma-tocopherol in rats treated with sodium dichromate
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