217964

Sigma-Aldrich

四丁基四氟硼酸铵

99%

线性分子式:
(CH3CH2CH2CH2)4N(BF4)
CAS号:
分子量:
329.27
Beilstein/REAXYS Number:
3577508
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

200

测定

99%

mp

155-161 °C (lit.)

溶解性

methanol: soluble 10%, clear, colorless

SMILES string

F[B-](F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1

InChI key

NNZZSJSQYOFZAM-UHFFFAOYSA-N

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相关类别

一般描述

四丁基四氟硼酸铵(TBATFB)是相转移催化剂。它可以通过30%四氟硼酸水溶液与40%氢氧化四丁基铵水溶液反应合成。四丁基四氟硼酸铵可充当电解质,抑制烷基硫代硫酸盐在金上自组装。

应用

四丁基四氟硼酸铵可用于以下研究:
  • 作为伏安法测定Δ(9)-四氢大麻酚(Δ(9)-THC)的支持电解质。
  • 合成生物相关的大环内酯Sansalvamide A。
  • 作为循环伏安法测定5,10,15,20-四[3-(3-三氟甲基)苯氧基]卟啉的氧化和还原电位的支持电解质。
  • 与1,10-菲咯啉制备1:1加合物。
  • 用于在水溶液中制备其他四丁基铵盐。
  • 作为合成导电性聚(噻吩)的电解质添加剂。

包装

5, 25, 100 g in poly bottle

象形图

CorrosionExclamation mark

警示用语:

Danger

hazcat

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

闪点(F)

No data available

闪点(C)

No data available

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书

原产地证书 (CofO)

Preparation and properties of novel polythiophenes containing 1,3-dithiol-2-ylidene moieties.
Kozaki M, et al.
The Journal of Organic Chemistry, 59(2), 442-450 (1994)
Marco Antonio Balbino et al.
Forensic science international, 221(1-3), 29-32 (2012-04-25)
A new voltammetric method for the determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC) is described. The voltammetric experiments were accomplished in N-N dimethylformamide/water (9:1, v/v), using tetrabutylammonium tetrafluoroborate (TBATFB) 0.1mol/L as supporting electrolyte and a glassy carbon disk electrode as the working electrode....
Aldrichimica Acta, 13, 55-55 (1980)
José Antonio Morales-Serna et al.
Organic & biomolecular chemistry, 8(21), 4940-4948 (2010-09-08)
A facile and mild macrolactonization reaction of ω-hydroxy acids was developed based on the transesterification of benzotriazole esters. Treatment of ω-hydroxy acids with 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) and 1-hydroxy benzotriazole (HOBT) in chloroform provided macrolactones in excellent yields. The reactions were...
Electropolymerization of thiophene with and without aniline in acetonitrile.
Can M, et al.
Turkish Journal of Chemistry, 22, 47-54 (1998)

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