224758

Sigma-Aldrich

三(2,2′——联吡啶二氯钌 (II) 六水合物

powder

别名:
三(2,2′-联吡啶)氯化钌(II) 六水合物, Ru(BPY)3, 三联吡啶氯化钌
Empirical Formula (Hill Notation):
C30H24Cl2N6Ru · 6H2O
CAS号:
分子量:
748.62
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

形式

powder

质量水平

100

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C (lit.)

photocatalyst activation

450 nm

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

InChI key

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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一般描述

三(2,2′-联吡啶)二氯化钌(II) 六水合物是一种金属络合物,被用作发光染料。处于基态的金属络合物能够被可见光激发,形成自旋允许激发态。该激发态经过无辐射去活化,非常快速地形成自旋禁阻长期发光激发态。它被广泛用于电发光设备中。

应用

有关更多信息,请访问 Teshik Yoon教授Corey Stephenson教授的教授和产品门户网站。
  • 合成用于氧化酶生物传感器的复合催化剂。
  • 用作生物分析中多重信号传导的发光体。
  • 用于活细胞中的氧气评估。

包装

250 mg in glass insert
1, 5 g in glass bottle

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

分析证书

原产地证书 (CofO)

A Theoretical and Experimental Framework for Understanding Electrogenerated Chemiluminescence (ECL) Emission at Bipolar Electrodes
Mavre F, et al
Analytical Chemistry, 81, 6218-6225 (2009)
Attapulgite Clay Combined with Tris(2,2'bipyridyl)ruthenium(II) for the Enhancement of the
Electrogenerated Chemiluminescence Sensing
Gu B. et al
International Journal of Electrochemical Science, 7, 6202-6213 (2012)
Old Molecules, New Concepts:[Ru (bpy) 3] 2+ as a Molecular Encoder-Decoder
Ceroni, P., Bergamini, G., & Balzani, V.
Angewandte Chemie (International Edition in English), 121(45), 8668-8670 (2009)
Novel organic-inorganic hybrid material based on tris (2, 2'-bipyridyl) dichlororuthenium (II) hexahydrate and Dawson-type tungstophosphate K 7[H4PW18O62]? 18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam, M., & Easton, E. B.
Sensors and Actuators B, Chemical, 161(1), 520-527 (2012)
Stéphanie Heux et al.
Applied and environmental microbiology, 77(19), 7040-7049 (2011-08-16)
Miniaturization and high-throughput screening are currently the focus of emerging research areas such as systems biology and systems biotechnology. A fluorescence-based screening assay for the online monitoring of oxygen and pH and a numerical method to mine the resulting online...
相关内容
Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.
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One major theme of research in the Yoon lab is the development of unique chemical transformations enabled by visible light photochemistry. A variety of transition metal photocatalysts responsive to visible light are known, and the Yoon lab has shown that their well understood photochemistry can be coupled to cycloadditions, arene oxidations, amine functionalizations, and thiol-ene reactions, among others.
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