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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.376 (lit.)
沸点
91 °C (lit.)
密度
0.735 g/mL at 25 °C (lit.)
官能团
amine
isonitrile
SMILES字符串
CC(C)(C)[N+]#[C-]
InChI
1S/C5H9N/c1-5(2,3)6-4/h1-3H3
InChI key
FAGLEPBREOXSAC-UHFFFAOYSA-N
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一般描述
据报道， 叔丁基异氰酸酯在锗（100）表面形成碳配价键。它还与金属形成络合物，并插入金属-碳键中，形成亚氨基酰基。
应用
叔丁基异氰酸酯被用于合成 香豆素、4H-色烯 和 异恶唑啉。它还被用于捕获2-环亚丙基-1,3-二酮。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Inhalation - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
28.4 °F - closed cup
闪点(°C)
-2 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Synthesis of coumarines and 4H-chromenes through the reaction of tert-butyl isocyanide and dialkyl acetylenedicarboxylates in presence of 2-hydroxybenzaldehydes.
Yavari I, et al.
Synthesis, 5, 679-682 (2004)
Habib Nasri et al.
Inorganic chemistry, 43(9), 2932-2942 (2004-04-27)
The addition of the strongly pi-bonding ligands CO or tert-butyl isocyanide to the low-spin five-coordinate iron(II) nitrite species [Fe(TpivPP)(NO2)]- (TpivPP = picket fence porphyrin) gives two new six-coordinate species [Fe(TpivPP)(NO2)(CO)]- and [Fe(TpivPP)(NO2)(t-BuNC)]-. These species have been characterized by single-crystal structure
D Bandyopadhyay et al.
Biochemistry, 35(5), 1500-1505 (1996-02-06)
The kinetics of tert-butyl isocyanide binding to the heme protein horseradish peroxidase (HRP) at 22 degrees C was examined on all time scales, from minutes to picoseconds, in aqueous borate buffer at pH 9.08. Unlike myoglobin (Mb) or hemoglobin, HRP
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), (13)(13), 1710-1720 (2008-03-21)
Single-crystal structural characterizations confirm the existence of the unusual 1 : 4 copper(I) halide : unidentate ligand adducts [Cu(CNt-Bu)4]X for X = Cl, Br (two forms), I (the chloride and one form of the bromide being solvated) with crystal packing
Journal of the Chemical Society. Chemical Communications, 189-189 (1987)
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