质量水平
100
reaction suitability
reaction type: Cross Couplings
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Hiyama Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
81-83 °C (lit.)
官能团
phosphine
SMILES string
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InChI
1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
InChI key
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
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包装
1, 5, 25, 250 g in glass bottle
应用
用于丙二腈与芳基卤化物的钯催化偶联反应的配体。大位阻膦配体，与 Pd(0)-三烯酸大环催化剂一起用于芳基溴化物和氯化物的 Suzuki 偶联反应。
该配体与镍可用作形成环戊烷化合物的关键中间体。
警示用语：
Warning
hazcat
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
storage_class_code
11 - Combustible Solids
WGK Germany
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synlett, 3167-3167 (2006)
Sensuke Ogoshi et al.
Journal of the American Chemical Society, 128(16), 5350-5351 (2006-04-20)
Cyclopropyl phenyl ketone underwent oxidative addition to Ni(PCy3) generated from Ni(cod)2 and PCy3 to give a nickeladihydropyran, which is a key intermediate for the Ni(0)-catalyzed homo- or heterocycloaddition to give cyclopentane compounds having two carbonyl substituents at the 1,3-position.
Synlett, 3001-3001 (2006)
Adrian Tlahuext-Aca et al.
Dalton transactions (Cambridge, England : 2003), 43(42), 15997-16005 (2014-09-19)
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic system shows low to moderate tolerance for fluoro-, trifluoromethyl-...
Sebastijan Kovačič et al.
Macromolecular rapid communications, 36(17), 1605-1611 (2015-07-15)
Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). The resulting HIPEs containing the MIL-100(Fe) nanoparticles (MIL: Materials of Institut Lavoisier) at the interface between the...
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