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Merck

305677

Sigma-Aldrich

叔丁基磷酸

98%

别名:

P-(1,1-Dimethylethyl)phosphonic acid

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About This Item

线性分子式:
(CH3)3CP(O)(OH)2
CAS号:
分子量:
138.10
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

mp

187-189 °C (lit.)

SMILES 字串

CC(C)(C)P(O)(O)=O

InChI

1S/C4H11O3P/c1-4(2,3)8(5,6)7/h1-3H3,(H2,5,6,7)

InChI 密鑰

OGDSVONAYZTTDA-UHFFFAOYSA-N

應用

tert-Butylphosphonic acid was used in preparation of:
  • dinuclear dicationic vanadium(IV) complexes
  • borophosphonate cages
  • hexanuclear copper(II) cages
  • soluble molecular copper(II) phosphonates

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Saskia Speed et al.
Inorganic chemistry, 51(12), 6842-6850 (2012-05-26)
The syntheses, structural characterization, and magnetic behavior of two new hexanuclear copper(II) complexes derived from R-phosphonic acids and 1,3-bis(dimethylamino)-2-propanol (Hbdmap) with formulas [Cu(6)(μ-bdmap)(3)(μ(3)-Ph-PO(3))(2)(μ(3)-O···H···μ(3)-O)(ClO(4))(2)(H(2)O)]·5H(2)O (1) and [Cu(6)(μ-bdmap)(3)(μ(3)-t-Bu-PO(3))(2)(μ(3)-O···H···μ(3)-O)(μ(1,3)-dca)(dca)(H(2)O)]·6H(2)O (2) (Ph-H(2)PO(3) = phenylphosphonic acid, t-Bu-H(2)PO(3) = tert-butylphosphonic acid, dca = dicyanamide) are reported.
Pius O Adelani et al.
Inorganic chemistry, 58(19), 12662-12668 (2019-09-13)
We report herein a general synthetic approach for designing uranyl coordination cages. Compounds 1 and 2 are constructed through a temperature-dependent and solvent-driven self-assembly. In both cases, the synthetic strategy involves in situ phosphonate ligand condensation into a flexible pyrophosphonate
E Fanizza et al.
Nanoscale, 8(6), 3350-3361 (2016-01-15)
Here a luminescent hybrid nanostructure based on functionalized quantum dots (QDs) is used as a fluorescent imaging agent able to target selectively mitochondria thanks to the molecular recognition of the translocator protein (TSPO). The selective targeting of such an 18
Vadapalli Chandrasekhar et al.
Inorganic chemistry, 51(10), 5605-5616 (2012-05-12)
A multicomponent synthetic strategy involving copper(II) ions, tert-butylphosphonic acid (t-BuPO(3)H(2)) and 3-substituted pyrazole ligands has been adopted for the synthesis of soluble molecular copper(II) phosphonates. The use of six different 3-substituted pyrazoles, 3-R-PzH [R = H, Me, CF(3), Ph, 2-pyridyl
Dipankar Sahoo et al.
Dalton transactions (Cambridge, England : 2003), 43(28), 10898-10909 (2014-06-06)
The reaction of vanadium(III) trichloride with tert-butylphosphonic acid (t-BuPO3H2) in the presence of 1,10-phenanthroline/2,2'-bipyridine as an ancillary ligand in acetonitrile at room temperature afforded two dinuclear dicationic vanadium(IV) complexes [(VO)2(phen)2{t-BuPO2(OH)}2(OH2)2]·2Cl [1] and [(VO)2(bipy)2{t-BuPO2(OH)}2(OH2)2]·2Cl [2]. On the other hand, when the

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