Merck
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416665

Sigma-Aldrich

叔丁基过氧化氢 溶液

5.0-6.0 M in decane

别名:
1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP
线性分子式:
(CH3)3COOH
CAS号:
分子量:
90.12
Beilstein:
1098280
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

质量水平

200

测定

55.4-65.1% (Thiosulphate, titration)

形式

liquid

reaction suitability

reagent type: oxidant

浓度

5.0-6.0 M in decane

杂质

<4% water

折射率

n20/D 1.402

密度

0.808 g/mL at 25 °C

储存温度

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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一般描述

叔丁基氢过氧化物是一种有机过氧化物,可用于氧化过程。

应用

叔丁基氢过氧化物可用于:
锇催化烯烃在碱性条件下的邻位羟基化
使用联萘酚作为手性助剂,将硫化物催化不对称氧化成亚砜
二苯并噻吩的氧化

包装

25, 100 mL in poly bottle

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

闪点(F)

109.4 °F - closed cup

闪点(C)

43 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

分析证书

请输入批号搜索分析证书(COA)。

原产地证书 (CofO)

请输入批号搜索原产地证书(COO)。

Oxidative desulfurization of fuel oil: Part I. Oxidation of dibenzothiophenes using tert-butyl hydroperoxide.
Wang D, et al.
Applied Catalysis A: General, 91-99 (2003)
Osmium catalyzed vicinal hydroxylation of olefins by tert-butyl hydroperoxide under alkaline conditions.
Sharpless KB and Akashi K
Journal of the American Chemical Society, 98(7), 1986-1987 (1976)
Catalytic asymmetric oxidation of sulfides to sulfoxides with tert-butyl hydroperoxide using binaphthol as a chiral auxiliary
Komatsu N, et al.
The Journal of Organic Chemistry, 58(17), 4529-4533 (1993)
Grace McCambridge et al.
Biomolecules, 9(2) (2019-03-03)
Circulating fatty acids (FAs) increase with obesity and can drive mitochondrial damage and inflammation. Nicotinamide nucleotide transhydrogenase (NNT) is a mitochondrial protein that positively regulates nicotinamide adenine dinucleotide phosphate (NADPH), a key mediator of energy transduction and redox homeostasis. The
Aldrichimica Acta, 12, 63-63 (1979)

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