464309

Sigma-Aldrich

全氟丁基甲基醚

99%, mixture of n- and iso-butyl isomers

别名:
HFE-7100, 甲基九氟丁醚, 九氟甲氧基丁烷, 甲氧基九氟丁烷, 甲氧基全氟丁烷
线性分子式:
CH3OCF2R, R = -CF2CF2CF3 or -CF(CF3)2
CAS号:
分子量:
250.06
Beilstein/REAXYS Number:
8768491
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

99%

折射率

n20/D 1.3 (lit.)

bp

60 °C (lit.)

mp

−135 °C (lit.)

密度

1.52 g/mL at 25 °C (lit.)

SMILES string

COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F.COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F

InChI

1S/2C5H3F9O/c1-15-5(13,14)3(8,9)2(6,7)4(10,11)12;1-15-5(13,14)2(6,3(7,8)9)4(10,11)12/h2*1H3

InChI key

OKIYQFLILPKULA-UHFFFAOYSA-N

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应用

甲氧基九氟丁烷可用作以下反应的溶剂:
  • 通过芳基和杂芳基格式试剂的亲电氟化合成各种芳基氟化物衍生物。
  • 将氟化两嵌段共聚物接枝到二氧化硅颗粒上。

包装

100, 500 mL in glass bottle

storage_class_code

12 - Non Combustible Liquids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

分析证书

原产地证书 (CofO)

Efficient synthesis of aryl fluorides.
Pazhamalai Anbarasan et al.
Angewandte Chemie (International ed. in English), 49(12), 2219-2222 (2009-12-17)
Li-Hsin Han et al.
Langmuir : the ACS journal of surfaces and colloids, 26(9), 6108-6110 (2010-03-31)
Three-dimensional organic microfabrication, an emerging technology, faces the challenge of lacking a sacrificial agent (SA) to temporarily support the formation of microscale geometries, which can be removed after a microstructure is constructed. In this study, an ultradense oil-in-organofluorine colloidal emulsion...
Howard C Knachel et al.
Magnetic resonance in chemistry : MRC, 51(7), 407-413 (2013-05-25)
The 3M Company product Novec™ 71IPA DL, a mixture of methoxyperfluorobutane, methoxyperfluoroisobutane and 4.5 wt.% isopropyl alcohol, has been found to be very stable at ambient temperature, producing fluoride at the rate of ~1 ppm/year. Our earlier kinetic and theoretical studies have...
Alfonso Bentolila et al.
Forensic science international, 278, 374-378 (2017-08-15)
Working in crime scenes presents a challenge to the forensic scientist, as some surfaces, such as floors and walls, cannot be transferred to the lab for further development and must, therefore, be processed at the crime scene itself. Two main...
Coating of silica particles by fluorinated diblock copolymers and use of the resultant silica for superamphiphobic surfaces
Grozea CM, et al.
Polymer, 64(12), 153-162 (2015)

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