510041

Sigma-Aldrich

Raney®-镍

W.R. Grace and Co. Raney® 4200, slurry, in H2O, active catalyst

别名:
海绵镍
线性分子式:
AlNi
CAS号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

形式

slurry

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 4200

浓度

in H2O

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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包装

100 g in poly bottle

应用

Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

法律信息

Raney is a registered trademark of W.R. Grace & Co.-Conn.

警示用语:

Danger

RIDADR

UN 1378 4.2 / PGII

WGK Germany

WGK 2

闪点(F)

Not applicable

闪点(C)

Not applicable

分析证书

原产地证书 (CofO)

Michał Sarul et al.
Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 22(2), 253-260 (2013-05-28)
Cognizance of the mechanical properties of nickel-titanium archwires is necessary for the management of orthodontic therapy with fixed appliances. Acting on the periodontium with forces that are too heavy may lead to such complications as: pain, tooth root resorption and...
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a...
A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the...
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)
Nitai Charan Giri et al.
Biochemistry, 52(24), 4168-4183 (2013-05-23)
Occupational and/or environmental exposure to nickel has been implicated in various types of cancer, and in vitro exposure to nickel compounds results in the accumulation of Ni(II) ions in cells. One group of major targets of Ni(II) ions inside the...

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