579726

Sigma-Aldrich

Grubbs Catalyst® M102

Umicore, 97%

别名:
双(三环己基膦)亚苄基钌(IV)二氯化物, 苯基亚甲基双(三环己基磷)二氯化钌, Grubbs Catalyst® M1a (C823), Grubbs Catalyst®第一代催化剂
Empirical Formula (Hill Notation):
C43H72Cl2P2Ru
CAS号:
分子量:
822.96
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

97%

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

153 °C (dec.)

储存温度

2-8°C

SMILES string

C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

应用

第一个被广泛用于有机合成的复分解催化剂。适用于在各种反应条件下的末端烯烃的无环二烯复分解聚合(ADMET)、应变环烯烃的开环复分解聚合(ROMP)、开环复分解(ROM)、烯烃交叉复分解(CM)和开环复分解(RCM)。

包装

1, 5, 50 g in glass bottle

法律信息

Umicore 产品

有关更多信息,请访问http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore

象形图

Flame

警示用语:

Warning

危险声明

预防措施声明

hazcat

Flam. Sol. 2

storage_class_code

4.1B - Flammable solid hazardous materials

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书

原产地证书 (CofO)

Dongwon Lee et al.
International journal of nanomedicine, 3(4), 471-476 (2008-01-01)
The overproduction of hydrogen peroxide is implicated in the progress of numerous life-threatening diseases and there is a great need for the development of contrast agents that can detect hydrogen peroxide in vivo. In this communication, we present a new...
Young-Woo Kim et al.
Nature protocols, 6(6), 761-771 (2011-06-04)
This protocol provides a detailed procedure for the preparation of stapled α-helical peptides, which have proven their potential as useful molecular probes and as next-generation therapeutics. Two crucial features of this protocol are (i) the construction of peptide substrates containing...
Schrodi, Y.; Pederson, R. L.
Aldrichimica Acta, 45-45 (2007)
T M Trnka et al.
Accounts of chemical research, 34(1), 18-29 (2001-02-15)
In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts are not only highly active but also...
Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.
Georgios C Vougioukalakis et al.
Chemical reviews, 110(3), 1746-1787 (2009-12-17)
技术文章
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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相关内容
烯烃复分解反应是一种有机反应,通过裂解和转变碳-碳双键,使链烯烃(烯烃)的片段重新分布。
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Research in the Grubbs group has centered on the development and application of a suite of highly active, selective, and bench stable ruthenium alkylidene complexes capable of catalyzing versatile olefin metatheses.
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