673587

Sigma-Aldrich

5,10,15,20-四(五氟苯基)-21H,23H-卟吩钯(II)

别名:
内消旋-四(五氟苯基)卟吩钯(II)
Empirical Formula (Hill Notation):
C44H8F20N4Pd
CAS号:
分子量:
1078.95
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

mp

>300 °C (dec.)

λmax

400 nm in acetone

storage temp.

−20°C

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Pd]n56

InChI

1S/C44H8F20N4.Pd/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;/h1-8H;/q-2;+2/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;

InChI key

GRRRJZUTYPIXFO-HQJDZOCDSA-N

General description

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II) is a phosphorescent dye that is a derivative of palladium(II). It can be used as a singlet oxygen sensitizer due to the presence of fluorine atoms. It provides photostability and is resistant to oxidation.

Application

It can be used as a porphyrin dye with a high quantum yield for use in the fabrication of oxygen sensors.

Packaging

100 mg in glass insert

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

A Robust Palladium (II)-Porphyrin Complex as Catalyst for Visible Light Induced Oxidative C? H Functionalization
To W, et al.
Chemistry?A European Journal , 19(18), 5654-5664 (2013)
Temperature-sensitive europium (III) probes and their use for simultaneous luminescent sensing of temperature and oxygen
Borisov SM and Wolfbeis OS
Analytical Chemistry, 78(14), 5094-5101 (2006)
Singlet oxygen-induced photodegradation of the polymers and dyes in optical sensing materials and the effect of stabilizers on these processes
Enko B, et al.
The Journal of Physical Chemistry A, 117(36), 8873-8882 (2013)
Composite luminescent material for dual sensing of oxygen and temperature
Borisov SM, et al.
Advances in Functional Materials, 16(12), 1536-1542 (2006)
Red light-excitable oxygen sensing materials based on platinum (II) and palladium (II) benzoporphyrins
Borisov SM, et al.
Analytical Chemistry, 80(24), 9435-9442 (2008)
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