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Merck

688886

Sigma-Aldrich

乙酰乙酸甲酯

Arxada quality, ≥99% (GC)

别名:

3-丁酮酸甲酯, 乙酰醋酸甲酯

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About This Item

线性分子式:
CH3COCH2COOCH3
CAS号:
分子量:
116.12
Beilstein:
506727
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥99% (GC)

形狀

liquid

自燃溫度

536 °F

品質

Arxada quality

製造商/商標名

Arxada AG

雜質

≤0.10% acid (as acetic acid)
≤0.10% water

顏色

APHA: ≤20

折射率

n20/D 1.419 (lit.)

bp

169-170 °C/70 mmHg (lit.)

mp

−80 °C (lit.)

密度

1.076 g/mL at 25 °C (lit.)

SMILES 字串

COC(=O)CC(C)=O

InChI

1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3

InChI 密鑰

WRQNANDWMGAFTP-UHFFFAOYSA-N

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象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

158.0 °F - closed cup

閃點(°C)

70 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xiao Hu et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(47), 16796-16801 (2014-11-05)
Much remains unknown regarding speciation. Host-pathogen interactions are a major driving force for diversification, but the genomic basis for speciation and host shifting remains unclear. The fungal genus Metarhizium contains species ranging from specialists with very narrow host ranges to
Solvej Siedler et al.
Applied microbiology and biotechnology, 93(4), 1459-1467 (2011-10-18)
Optimization of yields and productivities in reductive whole-cell biotransformations is an important issue for the industrial application of such processes. In a recent study with Escherichia coli, we analyzed the reduction of the prochiral β-ketoester methyl acetoacetate by an R-specific
L Sweetman et al.
Biomedical mass spectrometry, 5(3), 198-207 (1978-03-01)
A number of previously unrecognized abnormal metabolites have been identified and quantitated in the urine of a patient with an inherited deficiency of propionyl-CoA carboxylase. These included the isoleucine metabolites 2-methyl-3-hydroxybutyric acid and 2-methylacetoacetic acid. These isomers 3-hydroxyvaleric acid and
B H Robinson et al.
The Journal of pediatrics, 95(2), 228-233 (1979-08-01)
A female child presented at one year of age with a febrile illness and loose stools, then developed severe ketoacidosis with vomiting; an apparent salicylate level of 11 mg/dl was measured. A sibling had died in similar circumstances nine years
Marianne Ernst et al.
Applied microbiology and biotechnology, 66(6), 629-634 (2004-11-19)
A whole-cell biotransformation system for the reduction of prochiral carbonyl compounds, such as methyl acetoacetate, to chiral hydroxy acid derivatives [methyl (R)-3-hydroxy butanoate] was developed in Escherichia coli by construction of a recombinant oxidation/reduction cycle. Alcohol dehydrogenase from Lactobacillus brevis

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