718165

Sigma-Aldrich

三正辛基膦

97%

别名:
TOP, P(Oct)3
线性分子式:
[CH3(CH2)7]3P
CAS号:
分子量:
370.64
Beilstein/REAXYS Number:
1776995
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

折射率

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

密度

0.831 g/mL at 25 °C (lit.)

官能团

phosphine

SMILES string

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

RMZAYIKUYWXQPB-UHFFFAOYSA-N

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应用

三辛基膦可用于金属纳米晶、块状粉体、箔、线、薄膜向金属磷化物的转化。它还可以作为由醋酸镉和硫中合成硫化镉纳米棒反应的溶剂和稳定剂。

包装

100, 500 mL in Sure/Seal™
2 L in Sure/Seal™

象形图

Corrosion

警示用语:

Danger

危险声明

hazcat

Eye Dam. 1 - Skin Corr. 1B

storage_class_code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 2

闪点(F)

296.6 °F - closed cup

闪点(C)

147 °C - closed cup

分析证书

原产地证书 (CofO)

Trioctylphosphine as both solvent and stabilizer to synthesize CdS nanorods.
Chen S, et al.
Nanoscale Research Letters, 4(10), 1159-1159 (2009)
Jaehoon Lim et al.
Nature materials, 17(1), 42-49 (2017-11-29)
Chemically synthesized semiconductor quantum dots (QDs) can potentially enable solution-processable laser diodes with a wide range of operational wavelengths, yet demonstrations of lasing from the QDs are still at the laboratory stage. An important challenge-realization of lasing with electrical injection-remains...
Trioctylphosphine: a general phosphorus source for the low-temperature conversion of metals into metal phosphides.
Henkes AE & Schaak RE.
Chemistry of Materials, 19(17), 4234-4242 (2007)
Kimberly H Hartstein et al.
ACS nano, 11(10), 10430-10438 (2017-09-16)
We examine the effects of CdS shell growth on photochemical reduction of colloidal CdSe quantum dots (QDs) and describe the spectroscopic properties of the resulting n-type CdSe/CdS QDs. CdS shell growth greatly slows electron trapping. Because of this improvement, complete...
Tilman Läppchen et al.
EJNMMI physics, 7(1), 22-22 (2020-04-24)
For multicenter clinical studies, PET/CT and SPECT/CT scanners need to be validated to ensure comparability between various scanner types and brands. This validation is usually performed using hollow phantoms filled with radioactive liquids. In recent years, 3D printing technology has...

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