754730

Sigma-Aldrich

三(2,2′-联吡啶)钌(II)六氟磷酸盐

97%

别名:
钌-三(2,2′-联吡啶)二六氟磷酸盐, Ru(bpy)3(PF6)2
Empirical Formula (Hill Notation):
C30H24F12N6P2Ru
CAS号:
分子量:
859.55
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

质量水平

100

测定

97%

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

杂质

(Material is not fluorescence active.)

mp

>300 °C

photocatalyst activation

425 nm

吸光度

13,400 at 456 nm
80,000 at 291 nm

SMILES string

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2

InChI key

KLDYQWXVZLHTKT-UHFFFAOYSA-N

一般描述

三(2,2′-联吡啶)钌二(六氟磷酸)盐 (Ru(bpy)3(PF6)2)是一种导电聚合物,主要用作电化学器件中的活性层。它可促进高效低压器件形成。这种材料在3V时呈现了0.35和cd/m2的外部量子效率。

应用

Ru(bpy)3(PF6)2可用作共轭聚合物,用于开发基于发光电化学电池的器件,如发光二极管(LED)。它还被用作OLED/传感器研究的高效三重态发射极。

包装

1 g in glass bottle

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

分析证书

原产地证书 (CofO)

Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Direct measurement of the electric-field distribution in a light-emitting electrochemical cell
Slinker JD, et al.
Testing, 6(11), 894-894 (2007)
Wesley R Browne et al.
Journal of the American Chemical Society, 125(7), 1706-1707 (2003-02-13)
The excited-state properties of the transition metal complexes tris(2,2'-bipyridine) ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) are examined using picosecond time-resolved luminescence spectroscopy. For both complexes, direct observation of a short-lived high-energy emission with a lifetime of less than 4 ps is reported....
Valentina Leandri et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2...

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