761435

Sigma-Aldrich

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯

95%

别名:
甲磺酸[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II), [(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸酯, cataCXium-A-Pd-G3
Empirical Formula (Hill Notation):
C37H52NO3PPdS
CAS号:
分子量:
728.27
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

95%

特点

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

杂质

≤3% acetone

mp

196-241 °C (decomposition)

官能团

phosphine

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;

InChI key

REYVZCOGMIXVNX-DVBMAMJVSA-M

应用

cataCXium® A Pd G3是一种Buchwald第三代预催化剂,可用于:
  • 吡啶羧酸的直接邻位芳基化。
  • 在合成1-杂芳基-3-氮杂双环[3.1.0]己烷中催化Suzuki-Miyaura交叉偶联。
  • 钯催化的炔烃的羰基化碳全氟烷基化。
  • 在各种宝石-二取代的环丙烷合成中双生双(龙脑)环丙烷的Suzuki-Miyaura偶联反应。

包装

250 mg in glass bottle
1, 5 g in glass bottle

法律信息

cataCXium is a registered trademark of Evonik Degussa GmbH

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

分析证书

原产地证书 (CofO)

Direct ortho-Arylation of Pyridinecarboxylic Acids: Overcoming the Deactivating Effect of sp2-Nitrogen.
Johnston AJS, et al.
Organic Letters, 18(23), 6094-6097 (2016)
Construction of 1-Heteroaryl-3-azabicyclo [3.1. 0] hexanes by sp3-sp2 Suzuki-Miyaura and Chan-Evans-Lam Coupling Reactions of Tertiary Trifluoroborates.
Harris MR, et al.
Organic Letters, 19(9), 2450-2453 (2017)
A Modular Approach to the Synthesis of gem-Disubstituted Cyclopropanes.
Harris MR, et al.
Organic Letters, 20(10), 2867-2871 (2018)
The use of carboxylic acids as traceless directing groups for regioselective C-H bond functionalisation.
Font M and Quibell
Chemical Communications (Cambridge, England), 53(41), 5584-5597 (2017)
Pd-Catalyzed Carbonylative Carboperfluoroalkylation of Alkynes. Through-Space 13C-19F Coupling as a Probe for Configuration Assignment of Fluoroalkyl-Substituted Olefins.
Domanski S, et al.
The Journal of Organic Chemistry, 82(15), 7998-8007 (2017)
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