Merck

764221

Sigma-Aldrich

炔丙基-N-羟基琥珀酰亚胺酯

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别名:
2,5-二氧杂吡咯烷-1-基3-(丙-2-炔氧基)丙酸酯, 3-(2-丙炔-1-基氧基)丙酸2,5-二氧杂-1-吡咯烷基酯, 炔丙基琥珀酰亚胺基酯, 炔烃-NHS酯
Empirical Formula (Hill Notation):
C10H11NO5
分子量:
225.20
MDL编号:
PubChem化学物质编号:

形式

solid

质量水平

reaction suitability

reaction type: click chemistry
reagent type: cross-linking reagent

mp

36-41 °C

官能团

NHS ester
alkyne

储存温度

−20°C

SMILES string

C#CCOCCC(ON1C(CCC1=O)=O)=O

InChI

1S/C10H11NO5/c1-2-6-15-7-5-10(14)16-11-8(12)3-4-9(11)13/h1H,3-7H2

InChI key

WKIKHHMUNOVQLD-UHFFFAOYSA-N

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此商品
W295809792047633259
Propyl propionate ≥98%, FCC, FG

Sigma-Aldrich

W295809

丙酸丙酯

mp

36-41 °C

mp

−76 °C (lit.)

mp

135-140 °C

mp

133 °C (lit.)

storage temp.

−20°C

storage temp.

-

storage temp.

2-8°C

storage temp.

-

Quality Level

100

Quality Level

400

Quality Level

100

Quality Level

-

reaction suitability

reaction type: click chemistry

reaction suitability

-

reaction suitability

-

reaction suitability

-

functional group

NHS ester

functional group

-

functional group

-

functional group

-

应用

炔丙基-N-羟基琥珀酰亚胺酯可用作通过化学蛋白质组学方法鉴定亲核可配位热点的工具。
炔丙基-NHS酯是一种胺反应性试剂,用于肽、抗体、胺包被表面等的衍生化,具有一个末端炔烃。通过铜催化的叠氮化物-炔烃点击化学,炔烃可以与含叠氮化合物或生物分子反应,得到稳定的三唑键。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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NHS-Esters As Versatile Reactivity-Based Probes for Mapping Proteome-Wide Ligandable Hotspots.
Ward CC, et al.
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Zhu X, et al.
ACS Applied Materials & Interfaces (2017)
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ACS nano, 12(10), 10473-10485 (2018-10-06)
Multivalent presentation of ligands on nanoparticles (NPs) is considered a general strategy for enhancing receptor binding and activation through amplification of ligand-receptor interactions within the footprint of the individual NPs. The spatial clustering of ligand-functionalized NPs represents an additional, less
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Nature chemical biology, 16(4), 387-390 (2019-12-25)
Here, we report a rapid CRISPR-Cas9-mediated gene knock-in strategy that uses Cas9 ribonucleoprotein and 5'-modified double-stranded DNA donors with 50-base-pair homology arms and achieved unprecedented 65/40% knock-in rates for 0.7/2.5 kilobase inserts, respectively, in human embryonic kidney 293T cells. The identified

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