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About This Item
线性分子式:
(CH3CH2CH2CH2)4N(CN)
CAS号:
分子量:
268.48
Beilstein:
3598808
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22
推荐产品
應用
氰化四丁基胺可用作催化剂：
- 在质子溶剂存在下，用于脱保护脂肪族硫醋酸酯，以合成自由硫基
- 在三甲基氰硅烷（TMSCN）存在下，用于羰基化合物的O-TMS 氰硅化反应，以合成氰丙烷三甲基硅醚.
- 在乙腈的存在下，通过对β-内酰胺键裂合成γ内酰胺，进而实现β-内酰胺的环扩展.
訊號詞
Danger
危險分類
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
安全危害
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Tetrabutylammonium cyanide catalyzes the addition of TMSCN to aldehydes and ketones
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Benito Alcaide et al.
Organic letters, 7(18), 3981-3984 (2005-08-27)
Tetrabutylammonium cyanide (20 mol %) catalyzes ring expansion of 4-(arylimino)methylazetidin-2-ones 2 to 5-aryliminopyrrolidin-2-ones 3 through a novel N1-C4 bond cleavage of the beta-lactam nucleus. New, efficient one-pot protocols to enantiopure succinimide derivatives 3 and 4 from beta-lactam aldehydes 1 have
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Holmes B, et al.
Tetrahedron, 61, 12339-12342 (2005)
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The conversion of 3',5'-disilylated 2'-O-(methylthiomethyl)ribonucleosides to 2'-O-(phthalimidooxymethyl)ribonucleosides is achieved in yields of 66% to 94%. Desilylation and dephtalimidation of these ribonucleosides by treatment with NH(4)F in MeOH produce 2'-O-aminooxymethylated ribonucleosides, which are efficient in producing stable and yet reversible 2'-conjugates
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