Merck
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文件

900152

Sigma-Aldrich

2-[[(2-羧乙基)硫烷基硫代羰基]-硫烷基]丙酸

所有图片(2)
Empirical Formula (Hill Notation):
C7H10O4S3
CAS号:
870451-09-5
分子量:
254.35
MDL编号:
MFCD28126761
PubChem化学物质编号:
329769779

检测方案

95% (GC)

质量水平

100

形式

powder

mp

120-125 °C

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723274PH005438PH016816
2-[[(2-Carboxyethyl)sulfanylthiocarbonyl]-sulfanyl]propanoic acid

Sigma-Aldrich

900152

2-[[(2-羧乙基)硫烷基硫代羰基]-硫烷基]丙酸

4-Cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoic acid 97% (HPLC)

Sigma-Aldrich

723274

4-氰基-4-[(十二烷基硫烷基硫羰基)硫烷基]戊酸

{[(Nonyloxy)carbothioyl]sulfanyl}acetic acid AldrichCPR

Sigma-Aldrich

PH005438

{[(Nonyloxy)carbothioyl]sulfanyl}acetic acid

1-[(Propylamino)sulfonyl]-3-piperidinecarboxylic acid AldrichCPR

Sigma-Aldrich

PH016816

1-[(Propylamino)sulfonyl]-3-piperidinecarboxylic acid

form

powder

form

solid

form

-

form

powder

mp

120-125 °C

mp

64-68 °C

mp

-

mp

-

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

-

一般描述

  • 一种稳定的三硫代碳酸酯链转移剂（CTA），也称为RAFT剂，可用于控制自由基聚合中的链增长，产生具有明确分子量和低多分散性的聚合物。
  • 2-(2-十二烷基三硫代碳酸酯基)丙酸可用于控制丙烯酸、丙烯酸酯、丙烯酰胺、苯乙烯、甲基丙烯酸酯和甲基丙烯酰胺的均聚和共聚。它可溶于水性和有机介质（两亲性）。

注意

储存条件：室温，避光。

法律信息

仅限研究用途使用：参见 sigma-aldrich.com/raftlicense。专利：WO98/01478, WO99/311444。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

Certificates of Analysis (COA)

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Synthesis of Dual-Functional Poly(6-azidohexylmethacrylate) Brushes by a RAFT Agent Carrying Carboxylic Acid End Groups.
Cimen D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53, 1696-1706 (2015)
Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates: RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s.
Wang R, et al.
Macromolecules, 38, 9518-9525 (2005)
Substituent Effects on Trithiocarbonates-Mediated Polymerization of Styrene.
Journal of Applied Polymer Science, 111, 2011-2017 (2009)
A Continuous Flow Process for the Radical Induced End Group Removal of RAFT Polymers.
Hornung H, et al.
Macromolecular Reaction Engineering, 6, 246-251 (2012)
Thermo-responsive shell cross-linked PMMA-b-P(NIPAAm-co-NAS) micelles for drug delivery.
Chang C, et al.
International Journal of Pharmaceutics, 420(2), 333-340 (2011)
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