913219

Sigma-Aldrich

(S,S)-BABIBOP

别名:
(3S,3′S)-3,3′-Di-tert-butyl-2,2′,3,3′-tetrahydro-4,4′-bibenzo[d][1,3]oxaphosphole
Empirical Formula (Hill Notation):
C22H28O2P2
CAS号:
分子量:
386.40

form

powder

Quality Level

optical purity

ee: ≥99% (HPLC)

Application

(S,S)-BABIBOP is a P-chiral biaryl biphosphorus ligand used in Pd, Cu, and Rh-catalyzed asymmetric hydrogenations.

Legal Information

Sold in collaboration with Zejun Pharmaceuticals

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Olga V Zatolochnaya et al.
Chemical science, 9(19), 4505-4510 (2018-06-14)
A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution, simultaneously creating two contiguous stereogenic centers with...
Guisheng Li et al.
Organic letters, 20(7), 1725-1729 (2018-03-16)
Novel bidentate phosphine ligands BABIPhos featuring a biaryl bis-dihydrobenzooxaphosphole core are presented. Their synthesis was achieved via Pd-catalyzed reductive homocoupling of dihydrobenzooxaphosphole aryl triflates. An efficient route toward various analogues was also established, giving access to phosphines with different electronic...

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