跳转至内容
Merck
所有图片(2)

主要文件

查看所有文档

D7600

Sigma-Aldrich

双丙酮葡萄糖

98%

别名:

1,2,5,6-二异亚丙基-D-葡萄糖, 乙酰丙酮-D-葡萄糖, 二丙酮-D-葡萄糖

登录查看公司和协议定价
所有图片(2)

About This Item

经验公式（希尔记法）:
C12H20O6
CAS号:
582-52-5
分子量:
260.28
Beilstein:
84386
EC號碼:
209-486-0
MDL號碼:
MFCD00005544
分類程式碼代碼:
12352201
PubChem物質ID:
24894140
NACRES:
NA.22

品質等級

200

化驗

98%

形狀

powder

光學活性

[α]20/D −18°, c = 1% in H2O

mp

109-113 °C (lit.)

SMILES 字串

[H][C@@]1(O[C@H]2O[C@@H](O[C@@H]2[C@H]1O)C(Cl)(Cl)Cl)[C@H]3COC(C)(C)O3

InChI

1S/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1

InChI 密鑰

KEJGAYKWRDILTF-JDDHQFAOSA-N

應用

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose can be used as a starting material to prepare:
  • Biologically active L-acovenose, 6-deoxy-L-idose and, carbanucleoside enantiomers.
  • Vinyl ether-based chiral carbohydrate synthon by reacting with acetylene using superbase catalytic systems.
  • Fluoro-thiofuranosyl nucleosides of biological importance.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCK6751
MKBZ5297V
MKBT8903V
MKBK4060V
MKBD7675V

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

其他客户在看

Slide 1 of 1

1 of 1

苄基溴 reagent grade, 98%

Sigma-Aldrich

B17905

苄基溴

An efficient synthesis of 3-fluoro-5-thio-xylofuranosyl nucleosides of thymine, uracil, and 5-fluorouracil as potential antitumor or/and antiviral agents
Tsoukala E, et al.
Bioorganic & Medicinal Chemistry, 15(9), 3241-3247 (2007)
Direct vinylation of glucose derivatives with acetylene
Trofimov BA, et al.
Tetrahedron, 63(47), 11661-11665 (2007)
Carbanucleosides: synthesis of both enantiomers of 2-(6-chloro-purin-9-yl)-3, 5-bishydroxymethyl cyclopentanol from d-glucose
Roy BG, et al.
Tetrahedron Letters, 47(50), 8821-8825 (2006)
Guylaine M Defossemont et al.
Carbohydrate research, 338(6), 563-565 (2003-04-02)
The synthesis and characterisation of a novel chiral bicyclic oxacaprolactone is reported. The choice of diisopropylidene-D-glucose as a starting material allowed selective introduction of the synthetic equivalent necessary for the formation of the seven-membered ring of the lactone, i.e., one
S C Hung et al.
Carbohydrate research, 331(4), 369-374 (2001-06-12)
A practical route toward the synthesis of 6-deoxy-L-idose and L-acovenose from 1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose is described. Key steps include the stereoselective hydrogenation of 6-deoxy-1,2:3,5-di-O-isopropylidene-alpha-D-xylo-hex-5-enofuranose, regioselective protection of 6-deoxy-1,2-O-isopropylidene-beta-L-idofuranose at 0-5, and epimerisation of 6-deoxy-5-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-beta-L-idofuranose at C-3.
查看所有相关文献

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门