D91071

Sigma-Aldrich

苄基膦酸二乙酯

99%

别名:
NSC 62294, 苄基膦酸二乙酯, (二乙氧基膦甲基)苯
线性分子式:
C6H5CH2P(O)(OC2H5)2
CAS号:
分子量:
228.22
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

99%

reaction suitability

reaction type: C-C Bond Formation

折射率

n20/D 1.497 (lit.)

bp

106-108 °C/1 mmHg (lit.)

密度

1.095 g/mL at 25 °C (lit.)

SMILES string

CCOP(=O)(Cc1ccccc1)OCC

InChI

1S/C11H17O3P/c1-3-13-15(12,14-4-2)10-11-8-6-5-7-9-11/h5-9H,3-4,10H2,1-2H3

InChI key

AIPRAPZUGUTQKX-UHFFFAOYSA-N

应用

用于合成以下物质的反应物:
  • 3,5-二羟基-4-异丙基二苯乙烯(治疗皮肤疾病)
  • 通过分子内 Diels-Alder 反应来源的天然细胞毒性海产品
  • 邻二醇的柱上氧化和 Horner-Emmons 反应合成的二苯乙烯
  • Wnt 通路抑制剂(使用 Wadsworth-Emmons 反应抑制结肠癌)
  • 恶性疟原虫的抗疟药类似物

用作以下过程的反应物:
  • 芳基醚、胺和酰胺的环化
  • 研究官能团对线索有机发光二极管性能的影响

包装

25, 100 g in glass bottle

storage_class_code

12 - Non Combustible Liquids

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

Eyeshields, Gloves

分析证书

原产地证书 (CofO)

Ananya Thomas et al.
Polymers, 12(8) (2020-08-17)
As a part of our ongoing investigations on passively fire protecting polymeric materials, we have been employing both reactive and additive routes involving phosphorus-containing compounds. These included inorganic and organic substances, and in the latter case, the phosphorus-bearing groups differed...
Jack Saltiel et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2174-2179 (2019-05-28)
cis,trans-1,2-Dideuterio-1,4-diphenyl-1,3-butadiene (ct-DPBd2) was synthesized and its cis-trans photoisomerization in cyclohexane-d12 (C6D12) at room temperature was monitored by 1H NMR spectroscopy. The results reveal formation of only trans,trans-1,2-dideuterio-1,4-diphenyl-1,3-butadiene (tt-DPBd2). The failure to detect formation of trans,cis-1,2-dideuterio-1,4-diphenyl-1,3-butadiene (tc-DPBd2) eliminates the possibility that...

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