所有图片(1)

H8706

Sigma-Aldrich

六氟苯

99%

别名:
六氟苯
Empirical Formula (Hill Notation):
C6F6
CAS号:
分子量:
186.05
Beilstein:
1683438
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

99%

折射率

n20/D 1.377 (lit.)

bp

80-82 °C (lit.)

mp

3.7-4.1 °C (lit.)

密度

1.612 g/mL at 25 °C (lit.)

SMILES string

Fc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C6F6/c7-1-2(8)4(10)6(12)5(11)3(1)9

InChI key

ZQBFAOFFOQMSGJ-UHFFFAOYSA-N

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应用

六氟苯可与以下物质反应:
  • 在过渡金属卤化物存在下,与乙基溴化镁反应形成相应的全氟芳基镁化合物(可发生格氏反应)。
  • 在1,3-二甲基-2-咪唑烷酮(DMEU)中与适当苯酚的钠盐反应,形成六(芳氧基)苯。

它可以用于:
  • 作为合成新型钌(0)和锇(0)六氟苯配合物的配体。
  • 在存在钌催化剂时,作为闭环复分解(RCM)的溶剂和助催化剂,形成四取代烯烃。

包装

5, 25, 100 g in glass bottle

象形图

Flame

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(F)

50.0 °F - closed cup

闪点(C)

10 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析证书

原产地证书 (CofO)

Synthesis of hexakis (aryloxy) benzenes: x-ray analysis of hexakis (phenyloxy) benzene and of the acetonitrile clathrate of hexakis (3, 5-dimethylphenyloxy) benzene
Gilmore C J, et al.
Tetrahedron Letters, 24(31), 3269-3272 (1983)
Synthesis of new ? 4-hexafluorobenzene complexes of ruthenium and osmium from atoms of the metals: crystal structure of [Ru (? 6-C 6 H 3 Me 3-1, 3, 5)(? 4-C 6 F 6)]
Martin A, et al.
Journal of the Chemical Society, (15), 2251-2255 (1994)
A hexafluorobenzene promoted ring-closing metathesis to form tetrasubstituted olefins.
Rost D, et al.
Tetrahedron Letters, 49(41), 5968-5971 (2008)
Markus Allesch et al.
The journal of physical chemistry. B, 111(5), 1081-1089 (2007-02-03)
We report on the aqueous hydration of benzene and hexafluorobenzene, as obtained by carrying out extensive (>100 ps) first principles molecular dynamics simulations. Our results show that benzene and hexafluorobenzene do not behave as ordinary hydrophobic solutes, but rather present
Mariana Palma et al.
Frontiers in physiology, 11, 205-205 (2020-04-09)
Practical diets for commercial barramundi production rarely contain greater than 10% starch, used mainly as a binding agent during extrusion. Alternative ingredients such as digestible starch have shown some capacity to spare dietary protein catabolism to generate glucose. In the

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