P29006

Sigma-Aldrich

苯膦酸

98%

别名:
Benzene phosphonic acid
线性分子式:
C6H5P(O)(OH)2
CAS号:
分子量:
158.09
Beilstein/REAXYS Number:
2245168
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

质量水平

200

测定

98%

mp

162-164 °C (lit.)

SMILES string

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChI key

QLZHNIAADXEJJP-UHFFFAOYSA-N

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应用

苯基膦酸的自组装单分子膜 (SAMs) 可用于制备有机半导体与透明导电氧化物之间的界面。酸可用于使二氧化钛颗粒功能化。与 Noyor® 催化剂配合使用,用于硫化物绿色氧化为砜。
与 Noyori 催化剂配合使用,用于将硫化物氧化为砜类的添加剂。

Noyori 氧化(二水合钨酸钠、过氧化氢、甲基三正辛基硫酸氢铵、磷酸)

包装

5, 100, 500 g in glass bottle

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

hazcat

Acute Tox. 4 Oral - Skin Corr. 1B

storage_class_code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

分析证书

原产地证书 (CofO)

M W Fryer et al.
Journal of muscle research and cell motility, 18(2), 161-167 (1997-04-01)
The rate, magnitude and pharmacology of inorganic phosphate (Pi) transport into the sarcoplasmic reticulum were estimated in single, mechanically skinned skeletal muscle fibres of the rat. This was done, indirectly, by using a technique that measured the total Ca2+ content...
K Hendrich et al.
Journal of magnetic resonance. Series B, 105(3), 225-232 (1994-11-01)
Spatial localization with the spectroscopic imaging technique is normally implemented with the Fourier-transform approach, yielding rectangular voxels, with potentially significant cross-voxel contamination. Multidimensional Fourier-series window (FSW) is an alternate approach that generates single voxels of predetermined shape, with minimal out-of-voxel...
Pengju Pan et al.
ACS applied materials & interfaces, 1(2), 402-411 (2009-02-25)
Layered metal phosphonate, zinc phenylphosphonate (PPZn), reinforced poly(L-lactide) (PLLA) composites were fabricated by a melt-mixing technique. The nonisothermal and isothermal crystallization, melting behavior, spherulite morphology, crystalline structure, and static and dynamic mechanical properties of the PLLA/PPZn composites were investigated. PPZn...
Orientation of Phenylphosphonic Acid Self-Assembled Monolayers on a Transparent Conductive Oxide: A Combined NEXAFS, PM-IRRAS, and DFT Study
Gliboff M, et al.
Langmuir, 29(7), 2166?2174-2166?2174 (2013)
Christel Gervais et al.
Magnetic resonance in chemistry : MRC, 42(5), 445-452 (2004-04-20)
1H, 13C, 17O and 31P NMR parameters, including chemical shift tensors and quadrupolar parameters for 17O, were calculated for phenylphosphonic acid, C6H5PO(OH)2, under periodic boundary conditions. The results are in very good agreement with experimental data and permit the unambiguous...

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