T84603

Sigma-Aldrich

三苯基氧膦

98%

别名:
Ph3PO, 三苯基氧化膦, TPPO
线性分子式:
(C6H5)3PO
CAS号:
分子量:
278.28
Beilstein/REAXYS Number:
745854
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

200

测定

98%

reaction suitability

reagent type: ligand
reaction type: Coupling Reactions

reagent type: ligand
reaction type: Epoxidations

reagent type: ligand
reaction type: Michael Reaction

mp

150-157 °C (lit.)

官能团

phosphine

SMILES string

O=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

FIQMHBFVRAXMOP-UHFFFAOYSA-N

正在寻找类似产品? Visit 产品对比指南

应用

高三苯基氧化膦可用于:
  • 用作无环伯醇和仲醇的Appel型氯化反应的催化剂。
  • 用作α,β-不饱和酸酯和andβ,γ-不饱和酮酯α-化合物在立体选择性聚和二溴化的催化剂。
  • 用作启动子,通过乙醇与呋核亚硝脲碘化物的非对映选择性合成α呋喃糖苷

包装

25, 100 g in poly bottle

象形图

Exclamation mark

警示用语:

Warning

危险声明

hazcat

Acute Tox. 4 Oral - Aquatic Chronic 3

storage_class_code

11 - Combustible Solids

WGK Germany

WGK 2

闪点(F)

356.0 °F

闪点(C)

180 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书

原产地证书 (CofO)

Li Na Quan et al.
Nature communications, 11(1), 170-170 (2020-01-12)
Reduced-dimensional perovskites are attractive light-emitting materials due to their efficient luminescence, color purity, tunable bandgap, and structural diversity. A major limitation in perovskite light-emitting diodes is their limited operational stability. Here we demonstrate that rapid photodegradation arises from edge-initiated photooxidation...
Phosphine oxide-catalysed chlorination reactions of alcohols under Appel conditions
Denton RM, et al.
Chemical Communications (Cambridge, England), 46(17), 3025-3027 (2010)
Ya-Kun Wang et al.
Nature communications, 11(1), 3674-3674 (2020-07-24)
Metal halide perovskites have emerged as promising candidates for solution-processed blue light-emitting diodes (LEDs). However, halide phase segregation - and the resultant spectral shift - at LED operating voltages hinders their application. Here we report true-blue LEDs employing quasi-two-dimensional cesium...
?-Selective Ribofuranosylation of Alcohols with Ribofuranosyl Iodides and Triphenylphosphine Oxide
Oka N, et al.
The Journal of Organic Chemistry, 79(16), 7656-7664 (2014)
Stephen M Richoll et al.
Journal of chromatography. A, 1127(1-2), 147-153 (2006-07-04)
A versatile procedure has been developed and validated for the determination of triphenylphosphine oxide (TPPO) at low levels in various active pharmaceutical ingredients (APIs). This procedure incorporates the use of the novel hollow-fiber liquid-phase microextraction (LPME) for the measurement of...

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门