155837

Sigma-Aldrich

四丁基硫酸氢铵

97%

别名:
Tetrabutylammonium bisulfate
线性分子式:
(CH3CH2CH2CH2)4N(HSO4)
CAS号:
分子量:
339.53
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.21

质量水平

100

测定

97%

mp

169-171 °C (lit.)

SMILES string

OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

SHFJWMWCIHQNCP-UHFFFAOYSA-M

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相关类别

一般描述

四丁基硫酸氢铵是一种铵盐。它可以用作溶解钌(II)络合物 fac-[Ru(CO)2(H2O)3(C(O)C2H5)][CF3SO3]的溶剂。它可作为制备交替聚酮和丙酸的反应介质中的助催化剂。

应用

四丁基硫酸氢铵可用作糖基化1,4-二氢吡啶的绿色合成的催化剂。
四丁基硫酸氢铵可作为离子对试剂,通过气相色谱(GC)方法测定:
  • 直链烷基苯磺酸盐(LASs)
  • 酸性除草剂
四丁基硫酸氢铵可用作糖基化1,4-二氢吡啶的绿色合成的催化剂。

包装

25, 100 g in poly bottle
1 kg in poly bottle

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

hazcat

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1

storage_class_code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 2

闪点(F)

348.1 °F - closed cup

闪点(C)

175.6 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书

原产地证书 (CofO)

Environmental and bioanalytical applications of hollow fiber membrane liquid-phase microextraction: a review
Lee J, et al.
Analytica Chimica Acta, 624(2), 253-268 (2008)
Derivatization and solid-phase microextraction
Stashenko.EE and Martinez.RJ
TrAC, Trends in Analytical Chemistry, 23(8), 553-561 (2004)
Tetrabutylammonium hydrogen sulfate catalyzed eco-friendly and efficient synthesis of glycosyl 1, 4-dihydropyridines.
Tewari N, et al.
Tetrahedron Letters, 45(49), 9011-9014 (2004)
Hydrocarboxylation and stepwise alternating oligomerization of carbon monoxide and ethylene catalyzed by cis-[Rh(CO)2(amine)2](PF6) complexes in a wet liquid tetrabutylammonium hydrogensulfate.
Pardey AJ, et al.
Polyhedron, 23(10), 1677-1683 (2004)
New media in homogeneous catalysis: wet sodium or tetrabutylammonium hydrogensulfate salts for reppe syntheses catalyzed by a ru (ii) carbonyl complex.
Pardey AJ, et al.
Journal of Coordination Chemistry, 57(10), 871-882 (2004)

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