T19526

Sigma-Aldrich

四甲基氯化铵

reagent grade, ≥98%

别名:
TMA
线性分子式:
(CH3)4N(Cl)
CAS号:
分子量:
109.60
Beilstein/REAXYS Number:
3911201
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.21

质量水平

200

等级

reagent grade

测定

≥98%

mp

>300 °C (lit.)

SMILES string

[Cl-].C[N+](C)(C)C

InChI

1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1

InChI key

OKIZCWYLBDKLSU-UHFFFAOYSA-M

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相关类别

一般描述

四甲基氯化铵是一种季铵盐,由于其热稳定性和对强碱水溶液或亲核试剂的耐受性,通常用作催化剂。

应用

四甲基氯化铵与 N-羟基邻苯二甲酰亚胺和氧杂蒽酮可作为碳氢化合物有氧氧化生成相应含氧化合物的高效氯化物催化体系。它也可作为相转移催化剂,通过活性芳基氯化物与氟化钾在固-液相中的选择性氯/氟交换反应合成芳基氟化物。

包装

5 g in glass bottle
100, 500 g in poly bottle

警示用语:

Danger

hazcat

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Chronic 2 - Skin Irrit. 2 - STOT SE 1 Oral

靶器官

Central nervous system

storage_class_code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK Germany

WGK 1

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

分析证书

原产地证书 (CofO)

A free radical process for oxidation of hydrocarbons promoted by nonmetal xanthone and tetramethylammonium chloride under mild conditions.
Du Z, et al.
Tetrahedron Letters, 50(15), 1677-1680 (2009)
Tetramethylammonium chloride as a selective and robust phase transfer catalyst in a solid?liquid halex reaction: the role of water.
Sasson Y, et al.
Chemical Communications (Cambridge, England), 3, 297-298 (1996)
Min Bum Park et al.
Journal of the American Chemical Society, 135(6), 2248-2255 (2012-11-29)
A solid understanding of the molecular-level mechanisms responsible for zeolite crystallization remains one of the most challenging issues in modern zeolite science. Here we investigated the formation pathway for high-silica LTA zeolite crystals in the simultaneous presence of tetraethylammonium (TEA(+))...
Seonki Hong et al.
Science advances, 4(9), eaat7457-eaat7457 (2018-09-12)
Biological functions depend on biomolecular assembly processes. Assemblies of lipid bilayers, actins, microtubules, or chromosomes are indispensable for cellular functions. These hierarchical assembly processes are reasonably predictable by understanding chemical structures of the defined building blocks and their interactions. However...
Wei Shen et al.
Chemical communications (Cambridge, England), 49(73), 8114-8116 (2013-08-08)
A simple and low-cost colorimetric assay utilizing ferrofluidic nanoparticulate probes (FNPs) and a ligase for single-nucleotide polymorphism genotyping is described. Excellent sensitivity and selectivity were accomplished through the engagement of the FNPs and a ligase chain reaction.

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