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  • Novel bacterial molybdenum and tungsten enzymes: three-dimensional structure, spectroscopy, and reaction mechanism.

Novel bacterial molybdenum and tungsten enzymes: three-dimensional structure, spectroscopy, and reaction mechanism.

Biological chemistry (2005-10-13)
Matthias Boll, Bernhard Schink, Albrecht Messerschmidt, Peter M H Kroneck
摘要

The molybdenum enzymes 4-hydroxybenzoyl-CoA reductase and pyrogallol-phloroglucinol transhydroxylase and the tungsten enzyme acetylene hydratase catalyze reductive dehydroxylation reactions, i.e., transhydroxylation between phenolic residues and the addition of water to a triple bond. Such activities are unusual for this class of enzymes, which carry either a mononuclear Mo or W center. Crystallization and subsequent structural analysis by high-resolution X-ray crystallography has helped to resolve the reaction centers of these enzymes to a degree that allows us to understand the interaction of the enzyme and the respective substrate(s) in detail, and to develop a concept for the respective reaction mechanism, at least in two cases.

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钨, foil, thickness 0.127 mm, ≥99.9% trace metals basis
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钨, foil, thickness 0.25 mm, ≥99.9% trace metals basis
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钨, powder (monocrystalline), 0.6-1 μm, ≥99.9% trace metals basis
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钨, foil, thickness 0.5 mm, ≥99.9% trace metals basis
钨, wire reel, 5m, diameter 0.005mm, gold plated, 99.95%
钨, wire, straight, 1000mm, diameter 0.25mm, 99.9+%
钨, wire reel, 500m, diameter 0.125mm, clean, 99.95%
钨, wire reel, 10m, diameter 0.004mm, hard, clean, 99.95%
钨, foil, 100x100mm, thickness 0.125mm, as rolled, 99.95%
钨, foil, 100x100mm, thickness 0.15mm, as rolled, 99.95%
钨, foil, 100x100mm, thickness 0.1mm, as rolled, 99.95%
钨, foil, 100x100mm, thickness 0.2mm, as rolled, 99.95%
钨, foil, 100x100mm, thickness 0.3mm, as rolled, 99.95%
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