Merck
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177199

Sigma-Aldrich

Methyl propargyl ether

≥97%

Synonym(s):
3-Methoxy-1-propyne, Methyl 2-propynyl ether
Linear Formula:
HC≡CCH2OCH3
CAS Number:
Molecular Weight:
70.09
Beilstein:
878166
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥97%

form

liquid

refractive index

n20/D 1.396 (lit.)

bp

61-62 °C (lit.)

density

0.83 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COCC#C

InChI

1S/C4H6O/c1-3-4-5-2/h1H,4H2,2H3

InChI key

YACFFSVYSPMSGS-UHFFFAOYSA-N

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1 of 4

This Item
28309678960678201
Phenyl propargyl ether technical, ≥90% (GC)

Sigma-Aldrich

78960

Phenyl propargyl ether

Allyl methyl ether 97%

Sigma-Aldrich

678201

Allyl methyl ether

form

liquid

form

liquid

form

liquid

form

-

refractive index

n20/D 1.396 (lit.)

refractive index

n20/D 1.389 (lit.), n20/D 1.3896

refractive index

n20/D 1.535

refractive index

n20/D 1.3803

bp

61-62 °C (lit.)

bp

85-86 °C (lit.)

bp

-

bp

42-43 °C/760 mmHg

density

0.83 g/mL at 25 °C (lit.)

density

0.76-0.78 g/mL at 25 °C (lit.)

density

1.030 g/mL at 20 °C (lit.)

density

0.768 g/mL at 25 °C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

2-8°C

General description

The Raman spectra of methyl propargyl ether has been studied.

Application

Methyl propargyl ether was used in the synthesis of [Ru3(μ3-κ(2)-HNNMe2)(μ3-κ(2)-MeOCH2CCH2)(μ-CO)2(CO)6].

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-0.4 °F - closed cup

Flash Point(C)

-18 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Javier A Cabeza et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(20), 6040-6052 (2005-07-30)
The reactions of the hydrido-triruthenium cluster complex [Ru3(mu-H)(mu3-kappa(2)-HNNMe2)(CO)9] (1; H2NNMe2 = 1,1-dimethylhydrazine) with alkynes that have alpha-hydrogen atoms give trinuclear derivatives containing edge-bridging allyl or face-capping alkenyl ligands. Under mild conditions (THF, 70 degrees C) the isolated products are as
Conformational stability, barriers to internal rotation, ab initio calculations and vibrational assignment of methyl propargyl ether.
Journal of Molecular Structure, 320, 193-216 (1994)

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