281042

All Photos(1)

Tetradecafluorohexane

99%

All Photos(1)

Synonym(s):

Perfluorohexane

Linear Formula:

CF₃(CF₂)₄CF₃

CAS Number:

355-42-0

Molecular Weight:

338.04

Beilstein:

1802113

EC Number:

206-585-0

MDL number:

MFCD00000437

PubChem Substance ID:

24856965

NACRES:

NA.22

Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.252 (lit.)

bp

58-60 °C (lit.)

mp

-74 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

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1 of 4

This Item	379247	374334	439487
Sigma-Aldrich 281042 Tetradecafluorohexane	Sigma-Aldrich 379247 Tetradecafluorohexane	Sigma-Aldrich 374334 1,1,1,2-Tetrafluoroethane	Sigma-Aldrich 439487 1,1,1,2,2,3,3,7,7,8,8,9,9,9-Tetradecafluoro-4,6-nonanedione
assay 99%	assay 95%	assay ≥99%	assay 97%
form liquid	form liquid	form -	form -
refractive index n20/D 1.252 (lit.)	refractive index n20/D 1.252 (lit.)	refractive index -	refractive index n20/D 1.323 (lit.)
bp 58-60 °C (lit.)	bp 58-60 °C (lit.)	bp −26.5 °C (lit.)	bp 97 °C (lit.)
mp -74 °C (lit.)	mp -74 °C (lit.)	mp -	mp -
density 1.669 g/mL at 25 °C (lit.)	density 1.669 g/mL at 25 °C (lit.)	density -	density 1.64 g/mL at 25 °C (lit.)

General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane has been used:

as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
to investigate boiling heat transfer mechanisms
as a photosensitizer in fluorous biphasic singlet oxygenation
as a novel reaction medium for photooxidation reactions

Hazard Statements

H412

Precautionary Statements

P273 - P501

Hazard Classifications

Aquatic Chronic 3

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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