2-Fluorophenylboronic acid

Name: 2-Fluorophenylboronic acid
Brand: ALDRICH
Price: 4817.13 INR
Availability: InStock

≥95%

Synonym(s):

2-Fluorobenzeneboronic acid, o-fluoro-benzeneboronic acid

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About This Item

Linear Formula:

FC₆H₄B(OH)₂

CAS Number:

1993-03-9

Molecular Weight:

139.92

MDL number:

MFCD00674013

UNSPSC Code:

12352103

PubChem Substance ID:

24868168

NACRES:

NA.22

Key Documents

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Quality Level

100

Assay

≥95%

form

solid

mp

101-110 °C (lit.)

functional group

fluoro

SMILES string

OB(O)c1ccccc1F

InChI

1S/C6H6BFO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H

InChI key

QCSLIRFWJPOENV-UHFFFAOYSA-N

Related Categories

Boronic Acids & Derivatives

Chemical Synthesis

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1 of 4

This Item	441643	471925	445215
Sigma-Aldrich 445223 2-Fluorophenylboronic acid	Sigma-Aldrich 441643 3-Fluorophenylboronic acid	Sigma-Aldrich 471925 3,5-Difluorophenylboronic acid	Sigma-Aldrich 445215 2-Chlorophenylboronic acid
assay ≥95%	assay ≥95.0%	assay ≥95%	assay ≥95.0%
form solid	form -	form powder	form solid
mp 101-110 °C (lit.)	mp 214-218 °C (lit.)	mp 210-217 °C (lit.)	mp 92-102 °C (lit.)
functional group fluoro	functional group fluoro	functional group fluoro	functional group chloro
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100

Application

Reactant for:

Preparation of phenylboronic catechol esters as promising anion receptors for polymer electrolytes
Diastereoselective synthesis of trisubstituted allylic alcohols via rhodium-catalyzed arylation
Site-selective Suzuki-Miyaura arylation reactions
Rh-catalyzed enantioselective addition reactions
Rhodium- and Palladium-catalyzed substitution reactions

Used for the preparation of biologically active biphenyls[1] and arylboron difluoride Lewis acids.[2]

Other Notes

Contains varying amounts of anhydride

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The Journal of Organic Chemistry, 60, 3020-3020 (1995)

Helvetica Chimica Acta, 78, 2026-2026 (1995)

Developing and Comparing 2,6-Anthracene Derivatives: Optical, Electrochemical, Thermal, and Their Use in Organic Thin Film Transistors.

Mikhail Y Vorona et al.

Materials (Basel, Switzerland), 13(8) (2020-04-26)

Anthracene-based semiconductors have attracted great interest due to their molecular planarity, ambient and thermal stability, tunable frontier molecular orbitals and strong intermolecular interactions that can lead to good device field-effect transistor performance. In this study, we report the synthesis of

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2-Fluorophenylboronic acid