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902896

Sigma-Aldrich

Black phosphorus

>=20 micro gram/ml in NMP

Synonym(s):

2D Black phosphorus, Phosphorene

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About This Item

Linear Formula:
P
UNSPSC Code:
12161600
NACRES:
NA.23

form

liquid

General description

Black phosphorus, also known as phosphorene, is a stable allotrope of phosphorus with semiconducting properties. It has a good mechanical property and a tunable band structure. BP also has good anisotropic thermal, electrical and optical properties.

Application

BP is a two dimensional (2D) p-type material, which shows high hole mobility up to 1000 cm2V-1s-1. It can be used in the fabrication of energy storage devices such as lithium-ion batteries. BP can also be used in a variety of biomedical applications such as photodynamic therapy.
Owing to the unique properties such as thickness dependent tunable band gap, strong in-plane anisotropy, and high carrier mobility, 2D-black phosphorous has attracted significant attention recently. The applications of 2D-black phosphorous extend from electronics, to optoelectronics, spintronics, thermoelectrics and storage devices.

Caution

Material is very oxygen sensitive. Please handle under inert atmosphere.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 1

Flash Point(F)

closed cup

Flash Point(C)

closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices.
Pang J, et al.
Advanced Energy Materials, 8, 1702093-1702093 (2018)
Production of few-layer phosphorene by liquid exfoliation of black phosphorus.
Brent, et al.
Chemical Communications (Cambridge, England), 50, 13338-13341 (2014)
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility.
Liu H, et al.
ACS Nano, 8, 4033-4041 (2014)
2D black phosphorus for energy storage and thermoelectric applications
Zhang Y, et al.
Small, 13(28), 1700661-1700661 (2017)
Recent advances in synthesis, properties, and applications of phosphorene.
Akhtar M, et al.
NPJ 2D materials and applications, 5, 1-1 (2017)

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