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Merck

229636

Copper(II) nitrate hydrate

99.999% trace metals basis

Synonym(s):

Cupric nitrate hydrate

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5 G

¥7,690

25 G

¥18,800

100 G

¥36,600

¥7,690


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About This Item

Linear Formula:
Cu(NO3)2 · xH2O
CAS Number:
Molecular Weight:
187.56 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
221-838-5
MDL number:
Assay:
99.999% trace metals basis
Form:
crystals and lumps

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InChI key

VMKYLARTXWTBPI-UHFFFAOYSA-N

InChI

1S/Cu.2NO3.H2O/c;2*2-1(3)4;/h;;;1H2/q+2;2*-1;

SMILES string

O.[Cu++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

assay

99.999% trace metals basis

form

crystals and lumps

reaction suitability

core: copper

impurities

≤15.0 ppm Trace Rare Earth Analysis

mp

114.5 °C (dec.) (lit.)

storage temp.

2-8°C

Quality Level

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1 of 4

This Item
923087923079467855
form

crystals and lumps

form

crystals and lumps

form

crystals and lumps

form

crystalline

assay

99.999% trace metals basis

assay

≥99.9% trace metals basis

assay

≥99.99% trace metals basis

assay

≥99.99% trace metals basis

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

mp

114.5 °C (dec.) (lit.)

mp

114.5 °C (dec.) (lit.)

mp

114.5 °C (dec.) (lit.)

mp

-

impurities

≤15.0 ppm Trace Rare Earth Analysis

impurities

-

impurities

-

impurities

≤0.01% insolubles, <100 ppm total metallic impurities

application(s)

battery manufacturing

application(s)

-

application(s)

-

application(s)

battery manufacturing

Application

Copper(II) nitrate hydrate can be used:
  • As a precursor to prepare CuO nanoparticles with photocatalytic activity.[1]
  • As a starting material to synthesize delafossite CuGaO2(CGO)electrocatalyst for hydrogen evolution from water splitting.[2]
  • To catalyze oxidative coupling of 2,6-dimethylphenol to produce a polymer which is an important engineering material.[3]

General description

Copper(II) nitrate hydrate is a blue crystalline solid widely used in the field of nanomaterial synthesis and secondary batteries.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Group 1: Oxidizing solids + Nitrates + Hazardous rank I + 1st oxidizing solid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

229636-100G:4548173120447 + 229636-5G:4548173120461 + 229636-BULK: + 229636-25G:4548173120454 + 229636-VAR:

jan


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Photocatalytic activity of CuO nanoparticles incorporated in mesoporous structure prepared from bis(2-aminonicotinato) copper(II) microflakes
Azadeh Tadjarodi, et al.
Transactions of Nonferrous Metals Society of China, 3634-3642 (2015)
Hydrothermal synthesized delafossite CuGaO2 as an electrocatalyst for water oxidation
Han Gao, et al.
Frontiers of Optoelectronics, 15, 8-8 (2022)
Seongjun Park et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-04)
Additive interface materials for improved ionic polymer metal composite (IPMC) actuator performance are being investigated. In this study, three-dimensional carbon nanostructure/copper nanowire (3DC Cu-NW) with a novel structure was synthesized via low-pressure chemical vapor deposition. An IPMC actuator with a
Electrodeposition of 1.4-eV-bandgap p-copper (II) oxide film with excellent photoactivity.
Izaki M, et al.
Journal of the Electrochemical Society, 158(9), D578-D584 (2011)
Baesjou, P.J. et al.
Macromolecules, 32, 270-270 (1999)

Articles

The prevailing strategies for heat and electric-power production that rely on fossil and fission fuels are having a negative impact on the environment and on our living conditions.

ペロブスカイト型酸化物や関連物質は、その柔軟性の高さから、新たな熱電材料の探索や最適化に関する非常に大きな可能性を持っています。

Related Content

金属有機構造体(MOF)、およびMOF合成用リンカー化合物、金属塩類、SBUをご紹介します。MOFは、ガス吸着や分離をはじめとするさまざまな用途に応用可能な高表面積をもつ多孔性材料です。

PCP/MOFとは、金属イオンと有機物の配位結合を利用して多孔性構造を形成する、錯体化学を基盤とした材料です。様々な金属イオンとそれらを連結する架橋性の有機配位子を組み合わせることで、内部に空間を持つ結晶性高分子構造を作ることが可能です。

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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