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Merck

379875

Palladium(II) acetate

99.98% trace metals basis

Synonym(s):

Pd(OAc)2, [Pd(OAc)2]3

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1 G

¥23,600

5 G

¥92,900

¥23,600


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About This Item

Linear Formula:
Pd(OCOCH3)2
CAS Number:
Molecular Weight:
224.51
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
222-164-4
Beilstein/REAXYS Number:
6086766
MDL number:

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InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

SMILES string

CC(O[Pd]OC(C)=O)=O

assay

99.98% trace metals basis

form

powder

reaction suitability

reagent type: catalyst, core: palladium

mp

216.3-223.7 °C (dec.)

Quality Level

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1 of 4

This Item
520764683124921025
assay

99.98% trace metals basis

assay

≥99.9% trace metals basis

assay

-

assay

≥99.9% trace metals basis

form

powder

form

-

form

powder

form

-

mp

216.3-223.7 °C (dec.)

mp

216.3-223.7 °C (dec.)

mp

216.3-223.7 °C (dec.)

mp

200-251 °C (dec.)

reaction suitability

core: aluminum

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: C-H Activation

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

reaction suitability

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

General description

Palladium(II) acetate is an orange, brown, moderately water-soluble source of palladium. We provide palladium(II) acetate with a purity of 99.98% on a trace metals basis (< 250.0 ppm), making it ideal for a wide range of catalytic reactions.

Application

Palladium(II) acetate is used
  • As a precursor in the one-step solvothermal synthesis of carbon-supported PtPdCu nanoalloy catalysts, enabling the formation of uniform nanoparticles with enhanced catalytic activity and stability for fuel cell applications.
  • As a key catalyst in the Sonogashira–Hagihara cross-coupling reaction to synthesize microporous polymers, which are carbonized to produce high-performance porous carbon electrodes for supercapacitors and hydrogen evolution reactions.
  • As a precursor in the fabrication of metallic nanopatterns through focused ion beam-induced decomposition of spin-coated thin films, enabling the creation of conductive palladium nanostructures for applications in nanoelectronics and advanced lithography.

Features and Benefits

  • High palladium loading (46.2 - 48.6%) increases the availability of active sites for catalysis, leading to more efficient conversion of reactants into products as more palladium atoms are involved in the reaction.
  • Ultra-high purity (99.98% Trace Metals Basis) minimizes contamination, enhancing performance by reducing metal sintering, preventing irreversible reactions with catalytic species, and maintaining optimal electronic properties for better catalyst efficiency in palladium-sensitive applications.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

379875-5G: + 379875-1G: + 379875-BULK: + 379875-VAR:

jan


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Xu, J.; et al.
Journal of Nanoparticle Research, 7 (4-5), 449-467 (2005)
Jujjuri, S.; et al.
J. Catal., 239 (2), 486-500 (2006)
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 53(44), 11895-11899 (2014-09-11)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation
Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 52(48), 12669-12673 (2013-10-16)
Hu Kang et al.
Journal of the American Chemical Society, 128(18), 6194-6205 (2006-05-04)
A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining a very large first hyperpolarizability (beta).

Questions

1–6 of 6 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the solubility of Product 379875, Palladium (II) acetate?

    1 answer
    1. It is soluble in chloroform and acetone.  It will decompose in hydrochloric acid.  It is insoluble in water.

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  4. Is Product 379875, Palladium (II) acetate, really 99.98% pure?

    1 answer
    1. The purity of 99.98% is not the actual chemical purity, but rather the purity based on trace metal content.  A maximum of 300ppm total metallic impurities would be allowed.

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  5. What is the melting point of Product 379875, Palladium (II) acetate?

    1 answer
    1. The melting point of this product is approximately 680 deg C.

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  6. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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