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Merck

228036

OXONE®, monopersulfate compound

Synonym(s):

Potassium peroxymonosulfate

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5 G

¥5,590

100 G

¥6,760

1 KG

¥8,990

5 KG

¥33,700

25 KG

¥112,000

¥5,590


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About This Item

Linear Formula:
KHSO5 · 0.5KHSO4 · 0.5K2SO4
CAS Number:
Molecular Weight:
307.38
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
powder

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vapor pressure

<0.0000017 hPa

Quality Level

form

powder

reaction suitability

reagent type: oxidant

concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH

2.1 (77 °C, 30 g/L)

SMILES string

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

HJKYXKSLRZKNSI-UHFFFAOYSA-I

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1 of 4

This Item
91135675920P8131
form

powder

form

powder

form

powder

form

powder or crystals

Quality Level

200

Quality Level

-

Quality Level

100

Quality Level

200

pH

2.1 (77 °C, 30 g/L)

pH

2-3 (10 g/L in aqueous solution, pH <6.0)

pH

-

pH

6-9 (25 °C, 329 g/L)

vapor pressure

<0.0000017 hPa

vapor pressure

-

vapor pressure

-

vapor pressure

-

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

reagent type: oxidant

reaction suitability

-

concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

concentration

>4.0% (active oxygen, titration by Na2S2O3 )

concentration

~1.6% (active oxygen)

concentration

-

General description

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.[1]

Application

OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.[1]
Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.
A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants.

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

228036-5KG:4548173932798 + 228036-1KG:4548173932767 + 228036-5G:4548173932781 + 228036-BULK: + 228036-VAR: + 228036-25KG:4548173932774 + 228036-100G:4548173932750

jan


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Certificates of Analysis (COA)

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Atmos. Environ., Part A, 27A, 765-765 (1993)
J Rodríguez-Chueca et al.
Journal of hazardous materials, 372, 94-102 (2018-05-08)
This study explores the enhancement of UV-C tertiary treatment by sulfate radical based Advanced Oxidation Processes (SR-AOPs), including photolytic activation of peroxymonosulfate (PMS) and persulfate (PS) and their photocatalytic activation using Fe(II). Their efficiency was assessed both for the inactivation
Journal of chemical research. Synopses, 388-388 (1992)
Jiamin Hu et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 79(5), 911-920 (2019-04-27)
In this study, the difference in oxidative capacity for removing antibiotics and the mechanism between the Cu(II)/peroxymonosulfate (PMS)/UV and Cu(II)/persulfate (PDS)/UV systems were compared under various conditions. The optimal Cu(II) concentration in the Cu(II)/PMS/UV system was 30 μM, and in
Yifu Li et al.
Bioresource technology, 262, 294-301 (2018-05-08)
In this study, zero valent iron (ZVI) activated peroxymonosulfate (PMS) as novel technique (i.e. ZVI-PMS technology) was employed to enhance sludge dewatering. In optimal sludge dewatering conditions of ZVI and KHSO5 dosages, the specific resistance to filtration (SRF) was reduced

Articles

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Global Trade Item Number

SKUGTIN
228036-1KG04061838781178
228036-25KG04061835561773
228036-5G04061838781185
228036-100G04061838781161
228036-5KG04061832579290

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. do you need explosive rated fans to operate around Oxone?

    1 answer
    1. The Safety Data Sheet classifies this material as non-explosive therefore there is no need for explosive rated fans in order to operate around OXONE®, monopersulfate compound Product 228036-100G.

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