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Merck

186317

N,N-ジエチルホルムアミド

99%

別名:

N-Formyldiethylamine

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25 G

¥6,280

100 G

¥18,500

¥6,280


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この商品について

化学式:
HCON(C2H5)2
CAS番号:
分子量:
101.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-533-2
Beilstein/REAXYS Number:
1209392
MDL number:

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製品名

N,N-ジエチルホルムアミド, 99%

InChI key

SUAKHGWARZSWIH-UHFFFAOYSA-N

InChI

1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3

SMILES string

CCN(CC)C=O

assay

99%

form

liquid

refractive index

n20/D 1.434 (lit.)

bp

176-177 °C (lit.)

density

0.908 g/mL at 25 °C (lit.)

functional group

amide

Quality Level

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当該品目
14277840252405280
assay

99%

assay

95%

assay

≥95.0% (GC)

assay

99%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

bp

176-177 °C (lit.)

bp

130-133 °C (lit.)

bp

130-133 °C (lit.)

bp

-

density

0.908 g/mL at 25 °C (lit.)

density

0.859 g/mL at 25 °C (lit.)

density

0.859 g/mL at 25 °C (lit.)

density

-

refractive index

n20/D 1.434 (lit.)

refractive index

n20/D 1.400 (lit.)

refractive index

n20/D 1.397-1.401, n20/D 1.400 (lit.)

refractive index

-

form

liquid

form

liquid

form

-

form

powder

Application

N,N-ジエチルホルムアミドは金属有機構造体の合成に使用されました[1]。また多孔性立方形状のZnO粒子の合成において溶媒としても使用されました[2]

General description

N,N-ジエチルホルムアミドは、密閉反応器中ZnCl2存在下で芳香族o-アミノニトリルと縮合してキナゾリン-2,4(1H,3H)-ジオンを生成します[3]

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk

WGK 1

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

South African research into AIDS "cure" severely criticised.
P Sidley
BMJ (Clinical research ed.), 314(7083), 771-771 (1997-03-15)
Jiarong Li et al.
Organic letters, 11(6), 1193-1196 (2009-02-26)
A new and facile preparation of quinazoline-2,4(1H,3H)-diones was first reported which was the condensation of aromatic o-aminonitriles with DMF or N,N-diethylformamide in the presence of ZnCl(2) (0.5-10 mol %) at 190-200 degrees C in the sealed reactor.
Yingmu Zhang et al.
Dalton transactions (Cambridge, England : 2003), 47(34), 11806-11811 (2018-06-05)
A new luminescent mesoporous metal-organic framework (PCN-604) was successfully synthesized from trimetric clusters, Al3(O)(CH3COO)6, and pyridine-based tritopic linkers, 4,4',4''-(pyridine-2,4,6-triyl)tribenzoate (PTB), via a solvothermal reaction. The MOF with an MTN topology possesses remarkable aqueous and thermal stabilities. Due to the efficient
Yuxia Shen et al.
Advanced materials (Deerfield Beach, Fla.), 30(52), e1802497-e1802497 (2018-11-06)
Large-scale synthesis of van der Waals (vdW) metal-organic framework (MOF) nanosheets with controlled crystallinity and interlayer coupling strength is one of the bottlenecks in 2D materials that has limited its successful transition to large-scale applications. Here, scalable synthesis of mBDC
Yu Kimitsuka et al.
Inorganic chemistry, 52(24), 14028-14033 (2013-11-26)
A method for synthesizing porous cubic-shaped ZnO particles a few tens of micrometers in size is described on the basis of a pyrolytic conversion of Zn-terephthalate metal-organic frameworks (MOFs). MOF crystals were initially grown in solutions containing Zn(NO3)2·6H2O and terephthalic

資料

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

金属有機構造体は、簡単な合成方法を用いて代替エネルギー用途のための高表面積材料を提供します。

関連コンテンツ

PCP/MOFとは、金属イオンと有機物の配位結合を利用して多孔性構造を形成する、錯体化学を基盤とした材料です。様々な金属イオンとそれらを連結する架橋性の有機配位子を組み合わせることで、内部に空間を持つ結晶性高分子構造を作ることが可能です。

質問

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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