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Merck

697257

シアン化銅(I)ジ(塩化リチウム)錯体 溶液

in anhydrous tetrahydrofuran, liquid

別名:

Copper(I) cyanide di(lithium chloride)

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50 ML

¥33,800

¥33,800


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この商品について

化学式:
CuCN · 2LiCl
分子量:
174.35
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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製品名

シアン化銅(I)ジ(塩化リチウム)錯体 溶液, in anhydrous tetrahydrofuran

SMILES string

[Li]Cl.[Li]Cl.[Cu]C#N

InChI

1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2

InChI key

QGXKBLXNBYNHBV-UHFFFAOYSA-L

form

liquid

reaction suitability

core: copper
reagent type: catalyst

concentration

in anhydrous tetrahydrofuran

density

0.999 g/mL at 25 °C

Quality Level

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1 of 4

当該品目
718114703559696307
reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

-

reaction suitability

core: copper, reagent type: catalyst

form

liquid

form

liquid

form

liquid

form

powder

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

0.999 g/mL at 25 °C

density

0.956 g/mL at 25 °C

density

1.05 g/mL at 25 °C

density

-

concentration

in anhydrous tetrahydrofuran

concentration

0.5 M in THF

concentration

0.6 M in THF, 16 % (w/w)

concentration

-

Application

シアン化銅(I)ジ(塩化リチウム)錯体は、有機亜鉛[1][2]とグリニャール試薬を用いた金属交換反応による有機銅(I)試薬の合成に使用できます。[3]また、有機銅酸塩(I)試薬を調製するための前駆体としても有用です。

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

保管分類

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F - closed cup - Solvent

flash_point_c

-17 °C - closed cup - Solvent

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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試験成績書(COA)

Lot/Batch Number

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以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

TMPZnCl?LiCl: A new active selective base for the directed zincation of sensitive aromatics and heteroaromatics.
Mosrin M and Knochel P
Organic Letters, 11(8), 1837-1840 (2009)
Joel M Harris et al.
The Journal of organic chemistry, 68(11), 4371-4381 (2003-05-24)
2,5,6-Trisubstituted piperidines are readily prepared by a combination of an aza-Achmatowicz oxidation of a furyl-substituted benzenesulfonamide followed by a conjugate addition to the resulting 2H-pyridone and subsequent addition of various nucleophiles to a transient N-sulfonyliminium ion. The stereochemistry of the
Tomas Hudlicky et al.
The Journal of organic chemistry, 67(25), 8726-8743 (2002-12-07)
Biocatalytic approaches have yielded efficient total syntheses of the major Amaryllidaceae alkaloids, all based on the key enzymatic dioxygenation of suitable aromatic precursors. This paper discusses the logic of general synthetic design for lycoricidine, narciclasine, pancratistatin, and 7-deoxypancratistatin. Experimental details
Regioselective functionalization of trisubstituted pyridines using a bromine-magnesium exchange.
Ren H and Knochel P
Chemical Communications (Cambridge, England), 11(7), 726-728 (2006)
Krause, N.; Gerold, A.
Angewandte Chemie (International Edition in English), 36, 186-186 (1997)

質問

1–3/3 質問  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      役に立ちましたか?

  3. what is the concentration of the solution?

    1 回答
    1. The concentration specificastion for this solution is 0.95M - 1.10M. This value is lot specific and reported on the Certificate of Analysis. Please use the link below to access a sample or lot specific Certificate:
      https://www.sigmaaldrich.com/product/aldrich/697257#product-documentation

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