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Merck

B1252

三フッ化ホウ素-メタノール 溶液

14% in methanol

Boron trifluoride-methanol solution

別名:

三フッ化ホウ素-メタノール複合体, BF3 メタノール, BF3MeOH, トリフルオロボラン, フッ化ホウ素-メタノール, 三フッ化ホウ素-メタノール

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サイズを選択してください

5 ML

¥8,740

100 ML

¥8,790

250 ML

¥11,300

500 ML

¥12,900

1 L

¥21,700

¥8,740


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この商品について

化学式:
BF3 · MeOH
CAS番号:
分子量:
99.85
UNSPSC Code:
12352104
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3611499

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製品名

三フッ化ホウ素-メタノール 溶液, 14% in methanol

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

form

liquid

reaction suitability

reagent type: catalyst
core: boron

concentration

12-16% (titration by NaOH)
14% in methanol

density

0.859 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

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当該品目
1571613482161626
concentration

12-16% (titration by NaOH), 14% in methanol

concentration

~10% (~1.3 M)

concentration

49-53% ( by NaOH, titration), 50% w/w in methanol

concentration

13-15% boron trifluoride

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

-

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

density

0.859 g/mL at 25 °C

density

0.86 g/mL at 20 °C

density

1.203 g/mL at 25 °C

density

0.859 g/mL at 25 °C

reaction suitability

reagent type: catalyst
core: boron

reaction suitability

reagent type: derivatization reagent
reaction type: Esterifications

reaction suitability

-

reaction suitability

-

Application

アセトアニリドの脱アセチル化に使用されます。[1]また、異なる種類のシアニン系色素[2]を含むアミノ基の合成の研究、および脂肪酸メチルエステルの調製に使用されます。[3]

General description

トリフルオロボラン-メタノール(BF-M)は、エステル化試薬です。BF-Mは、脂肪酸のエステル化のための強力な酸触媒です。アセチル化された色素を容易に開裂し、フリーのアミノ基を生成します。[2]BF-Mは、植物油のトランスエステル化を触媒し、バイオディーゼルを生成します。

Packaging

ねじブタ付き瓶

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

target_organs

Eyes,Central nervous system, Kidney

保管分類

3 - Flammable liquids

wgk

WGK 3

flash_point_f

49.5 °F

flash_point_c

9.7 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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文書ライブラリにアクセスする

Eun-Young Kim et al.
Molecular neurobiology, 57(9), 3860-3874 (2020-07-03)
Early life and adulthood stress increase vulnerability for mental illness, and eventually trigger depression. N-3 polyunsaturated fatty acids (PUFA) have antidepressant effects, but their effect on rats exposed to combined stress has been not investigated. This study aimed to investigate
Martin Trépanier et al.
Applied and environmental microbiology, 71(9), 5341-5347 (2005-09-10)
Lipids are the major form of carbon storage in arbuscular-mycorrhizal fungi. We studied fatty acid synthesis by Glomus intraradices and Gigaspora rosea. [(14)C]Acetate and [(14)C]sucrose were incorporated into a synthetic culture medium to test fatty acid synthetic ability in germinating
Deacylation of N-Acetylated Amines with Alcohol and Boron Trifluoride.
Acta Chemica Scandinavica, 8, 529-530 (1954)
Boron trifluoride-methanol complex-mild and powerful reagent for deprotection of labile acetylated amines.
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Donghee Kim et al.
The British journal of nutrition, 121(2), 137-145 (2018-12-07)
Conversion of α-linolenic acid (ALA) into the longer chain n-3 PUFA has been suggested to be affected by the dietary intake of linoleic acid (LA), but the mechanism is not well known. Therefore, the purpose of this study was to

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Product Information Sheet

質問

1–2/2 質問  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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