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Merck

328634

NMP

anhydrous, 99.5%

1-Methyl-2-pyrrolidinone
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別名:

1-メチル-2-ピロリドン, N-メチル-2-ピロリドン, M-PYROL, NMP

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サイズを選択してください

100 ML

¥7,010

1 L

¥15,300

2 L

¥26,500

¥7,010


在庫あり出荷可能詳細


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この商品について

実験式(ヒル表記法):
C5H9NO
CAS番号:
分子量:
99.13
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
212-828-1
MDL number:
Beilstein/REAXYS Number:
106420
Assay:
99.5%
Grade:
anhydrous
Bp:
202 °C (lit.), 81-82 °C/10 mmHg (lit.)
Vapor pressure:
0.29 mmHg ( 20 °C), 0.99 mmHg ( 40 °C)

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製品名

1-メチル-2-ピロリジノン, anhydrous, 99.5%

InChI key

SECXISVLQFMRJM-UHFFFAOYSA-N

InChI

1S/C5H9NO/c1-6-4-2-3-5(6)7/h2-4H2,1H3

SMILES string

CN1CCCC1=O

grade

anhydrous

vapor density

3.4 (vs air)

vapor pressure

0.29 mmHg ( 20 °C), 0.99 mmHg ( 40 °C)

assay

99.5%

form

liquid

autoignition temp.

518 °F

expl. lim.

9.5 %

impurities

<0.005% water

refractive index

n20/D 1.47 (lit.)

pH

7.7-10.0 (20 °C, 100 g/L)

bp

202 °C (lit.), 81-82 °C/10 mmHg (lit.)

mp

−24 °C (lit.)

density

1.028 g/mL at 25 °C (lit.)

Quality Level

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当該品目
493224437785.43899
Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

grade

anhydrous

grade

-

grade

ACS reagent

grade

-

assay

99.5%

assay

≥99.0% (GC)

assay

≥99.0%

assay

≥99.5% (GC)

form

liquid

form

liquid

form

liquid

form

liquid

vapor density

3.4 (vs air)

vapor density

3.4 (vs air)

vapor density

3.4 (vs air)

vapor density

-

expl. lim.

9.5 %

expl. lim.

9.5 %

expl. lim.

9.5 %

expl. lim.

1.3-9.5 % (v/v)

Application

1-メチル-2-ピロリジノンは、以下のプロセスにおける溶媒として使用されることがあります:
  • 2-アリールおよび2-アルキルベンゾチアゾールの調製。[1]
  • 2,2,6,6-テトラメチルヘプタン-3,5-ジオン存在下、ハロゲン化アリルおよびフェノールのUllmannカップリングによる、Ullmannエステルの生成。[2]
  • 共触媒としてのヨウ化銅の存在下、Pd/Cによって触媒されるヨウ化アリルの有機スタンナンとのStilleクロスカップリング反応。[3]

Packaging

通い容器のオプションをご覧ください。

Other Notes

Pure-Pac® II容器には、溶媒分注用のMicromatic MacroValveカプラー(製品番号Z560723)が必要です。

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

保管分類

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

195.8 °F - Pensky-Martens closed cup

flash_point_c

91 °C - Pensky-Martens closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

第一種指定化学物質

prtr

第4類:引火性液体 + 第三石油類 + 危険等級III + 水溶性液体

fsl

名称等を表示すべき危険物及び有害物

ishl_indicated

名称等を通知すべき危険物及び有害物

ishl_notified

328634-VAR: + 328634-4X2L:4548173987927 + 328634-8L: + 328634-200L: + 328634-250ML: + 328634-BULK: + 328634-1L:4548173987934 + 328634-2L:4548173987965 + 328634-18L-P1: + 328634-PZ: + 328634-100ML:4548173987958 + 328634-50L-P2: + 328634-6X1L:4548173987910 + 328634-200L-P2: + 328634-12X100ML:4548173987941 + 328634-20L: + 328634-18L:4548173987903 + 328634-PH-20L-P2: + 328634-900ML:

jan


最新バージョンのいずれかを選択してください:

試験成績書(COA)

Lot/Batch Number

適切なバージョンが見つかりませんか。

特定のバージョンが必要な場合は、ロット番号またはバッチ番号で特定の証明書を検索できます。

以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

Preparation of 1-methoxy-2-(4-methoxyphenoxy)benzene
Buck E and Song ZJ
Organic Syntheses, 82, 69-69 (2005)
Effects of additional multiwall carbon nanotubes on impact behaviors of LiNi0.5Mn0.3Co0.2O2 battery electrodes.
Le AV, et al.
Journal of Applied Physics, 118(8), 085312-085312 (2015)
Gerrit Homann et al.
iScience, 23(6), 101225-101225 (2020-06-21)
Frequently, poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) reveal a failure with high-voltage electrodes, e.g. LiNi0.6Mn0.2Co0.2O2 in lithium metal batteries, which can be monitored as an arbitrary appearance of a "voltage noise" during charge and can be attributed to Li
Stille couplings catalyzed by palladium-on-carbon with CuI as a cocatalyst: Synthesis of 2-(4'-acetylphenyl)thiophene
Liebeskind LS and Pe?a-Cabrera E
Organic Syntheses, 77, 135-135 (2000)
Guohua Hu et al.
Nature communications, 8(1), 278-278 (2017-08-19)
Black phosphorus is a two-dimensional material of great interest, in part because of its high carrier mobility and thickness dependent direct bandgap. However, its instability under ambient conditions limits material deposition options for device fabrication. Here we show a black

プロトコル

Guide for fabricating NMC811 cathode electrodes, detailing procedures for optimal performance in lithium-ion batteries.

Analysis of high- to moderate-nickel cathode materials for lithium-ion batteries, focusing on performance, stability, and structural characteristics.

質問

1–7/7 質問  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      役に立ちましたか?

  2. Is NMP compatible with PTFE?

    1 回答
    1. N-Methylpyrrolidone (NMP) is a commonly used solvent, and it is compatible with polytetrafluoroethylene (PTFE).

      役に立ちましたか?

  3. Is NMP supplied under N2 or air?

    1 回答
    1. This product is packaged under nitrogen.

      役に立ちましたか?

  4. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      役に立ちましたか?

  5. Is this NMP suitable for HPLC and GC analysis?

    1 回答
    1. Yes, this product is suitable for HPLC and GC analysis. This anhydrous NMP can be effectively used in environments where moisture must be minimized, which is often critical in analytical techniques like HPLC and GC.

      役に立ちましたか?

  6. Does it have molecular shieve in the bottle?

    1 回答
    1. Molecular sieves are not included with this anhydrous material. However, the 18L size is packaged in the Pure-Pac II container, and the 100 mL to 2L volumes utilize Sure/Seal closures. Please see the links below to learn more about each package type:

      Sure/Seal
      https://www.sigmaaldrich.com/technical-documents/technical-article/chemistry-and-synthesis/organic-reaction-toolbox/sureseal

      Pure-Pac
      https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/product/documents/391/402/al_techbull_al201.pdf

      役に立ちましたか?

  7. Could you please provide me with the dimensions of the bottle containing the product 328634-2L (1-Methyl-2-pyrrolidinone)?

    1 回答
    1. The packaging description for the bottle is as follows:
      • Bottle Type: Narrow Neck Glass Bottle
      • Capacity: 2500 ml (Nominal), 2750 ml (Brimful)
      • Closure Type: Crown Cap (Sure/Seal)
      • Glass Type: Amber Glass (Hydrolytic Class III)
      • Diameter: 139 mm
      • Height: 286 mm
      • Height with Cap: 293 mm
      • Thread Diameter: 32 mm
      • Thread Type: 32 mm
      • Inner Diameter of Opening: 17 mm

      役に立ちましたか?

レビュー

アクティブなフィルタ

  1. boston, ma
    • 2件のレビュー
    • 4件の投票
    星4/5個です。

    nice but also

    good product, but inconsistent stock. Many times unavailable.

    Googleで翻訳する

    役に立ちましたか?

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