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単分散ポリマー球の調製
コロイド結晶鋳型として使用できる単分散かつ表面活性剤を含まないポリマー球を簡便に作製することができます。代表的な乳化剤フリー合成法によるポリメタクリル酸メチルやポリスチレンの調製法を用いて、直径数百ナノメートルの球を作製します。
ATRPの典型的な重合方法
ATRP(原子移動ラジカル重合)によるPMMAおよびPSの典型的な重合手順をご紹介します。
RAFT剤を用いた典型的な重合反応例
RAFT(可逆的付加-開裂連鎖移動)重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。
ARGET ATRP: Procedure for PMMA Polymer Brush Growth
We presents an article about ARGET ATRP, and its procedure for PMMA polymer brush growth. Surface preparation before polymer brush growth consists of two steps: surface cleaning and initiator monolayer deposition.
RAFT Polymerization Procedures
RAFT (Reversible Addition-Fragmentation chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a suitable chain transfer (RAFT) reagent.
Typical Procedures for Polymerizing via RAFT
We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.
Typical Procedures for Polymerizing via ATRP
An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Preparation of Monodisperse Polymer Spheres
Monodisperse, surfactant-free polymer spheres for use as colloidal crystal templates can be easily obtained in reasonably large quantities. Typical synthesis methods for poly(methyl methacrylate) (PMMA) and poly(styrene) (PS) by emulsifier free emulsion polymerization are described below and yield spheres several
Concepts and Tools for RAFT Polymerization
We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.