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[BTF performance treating a chlorobenzene-contaminated gas stream].

Huan jing ke xue= Huanjing kexue (2012-04-04)
Qing-Wei Zhou, Run-Ye Zhu, Jun Hu, Li-Li Zhang, Jian-Meng Chen
ABSTRACT

In this study, biotrickling filter (BTF) inoculated with acclimated sludge was established to treat waste gas containing chlorobenzene. The BTF performance, average well color development (AWCD) values and microbial community were examined in steady state. Results revealed BTF achieved removal efficiency more than 80% of chlorobenzene under the conditions of < 0.6 g x m(-3) inlet concentration and > 45 s EBRT. Therefore, BTF have an advantage in treating low-concentration waste gas containing chlorobenzene (< or = 0.6 g x m(-3)). The overall chlorobenzene elimination capacity reached a maximum of 70 g x (m3 x h)(-1) at an inlet load of 80 g x (m3 x h)(-1). The mass ratio of carbon dioxide produced to the BTo-X removed was approximately 1.92, which confirms complete degradation of chlorobenzene, given that some of the organic carbon consumed is also used for the microbial growth. The degradation of chlorobenzene in the BTF followed Michaelis-Menten kinetic model, the maximum specific degradation rate (r(max)) was 35.6 g x (m3 x h)(-1). The AWCD values indicated that the microorganisms in the BTF showed high the microbial metabolic activity. The PCR-DGGE fingerprinting analysis on biofilm samples in the BTF indicated that the microbial community had a relative stability and complexity during the steady-state phase. The stability and complexity of microbial community could contribute to the degradation and mineralization of chlorobenzene in BTF.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Chlorobenzene, ReagentPlus®, 99%
Sigma-Aldrich
Chlorobenzene, suitable for HPLC, 99.9%
Sigma-Aldrich
Chlorobenzene, anhydrous, 99.8%
Sigma-Aldrich
Chlorobenzene, ACS reagent, ≥99.5%
Supelco
Chlorobenzene, analytical standard