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  • Colloidal templating at a cholesteric-oil interface: assembly guided by an array of disclination lines.

Colloidal templating at a cholesteric-oil interface: assembly guided by an array of disclination lines.

Physical review letters (2013-05-21)
J S Lintuvuori, A C Pawsey, K Stratford, M E Cates, P S Clegg, D Marenduzzo
ABSTRACT

We simulate colloids (radius R ~ 1 μm) trapped at the interface between a cholesteric liquid crystal and an immiscible oil at which the helical order (pitch p) in the bulk conflicts with the orientation induced at the interface, stabilizing an ordered array of disclinations. For a weak anchoring strength W of the director field at the colloidal surface, this creates a template, favoring particle positions either on top of or midway between defect lines, depending on α=R/p. For small α, optical microscopy experiments confirm this picture, but for larger α no templating is seen. This may stem from the emergence at moderate W of a rugged energy landscape associated with defect reconnections.

MATERIALS
Product Number
Brand
Product Description

Supelco
Melamine, Pharmaceutical Secondary Standard; Certified Reference Material
Sigma-Aldrich
Melamine, 99%
Supelco
Melamine, analytical standard