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377996

Titanium(IV) isopropoxide

99.999% trace metals basis

Synonym(s):

TTIP, Tetraisopropyl orthotitanate

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About This Item

Linear Formula:
Ti[OCH(CH3)2]4
CAS Number:
Molecular Weight:
284.22
UNSPSC Code:
12352107
NACRES:
NA.23
PubChem Substance ID:
EC Number:
208-909-6
Beilstein/REAXYS Number:
3679474
MDL number:
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Quality Segment

assay

99.999% trace metals basis

form

liquid

reaction suitability

core: titanium, reagent type: catalyst

refractive index

n20/D 1.464 (lit.)

bp

232 °C (lit.)

mp

14-17 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

SMILES string

CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI

1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

InChI key

VXUYXOFXAQZZMF-UHFFFAOYSA-N

General description

Titanium(IV)isopropoxide is a high-purity, colorless to yellowish liquid with a pungentodor. It is a colorless to yellowish liquid with a pungent odor. This compoundis used in various applications such as producing high-quality titanium dioxidefilms on glass and in electronics to produce thin-film transistors. It is alsoused in the production of specialty polymers, ceramics, and in organicsynthesis.

Application

Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

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This Item
20527387560687502
description

99.999% trace metals basis

description

97%

description

≥97.0%

description

packaged for use in deposition systems

form

liquid

form

liquid

form

liquid

form

liquid

assay

99.999% trace metals basis

assay

97%

assay

≥97.0%

assay

99.999%

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

refractive index

n20/D 1.464 (lit.)

refractive index

n20/D 1.464 (lit.)

refractive index

n20/D 1.464 (lit.)

refractive index

n20/D 1.464 (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)


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pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

105.8 °F - Pensky-Martens closed cup

flash_point_c

41 °C - Pensky-Martens closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–7 of 7 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Does the reagent come in a bottle with a septum?

    1 answer
    1. This product packaging does not include a septum cap. The item is supplied in an HPDE bottle with a screw cap.

      Helpful?

  4. Product 377996, Titanium (IV) isopropoxide is slightly yellow and it has always been colorless in the past.

    1 answer
    1. While many lots have passed as a colorless liquid, our specifications will also allow for a slightly yellow liquid (up to 25 APHA).

      Helpful?

  5. Sometimes I receive Product 377996, Titanium (IV) isopropoxide as a solid and sometimes as a liquid. Which is correct?

    1 answer
    1. The melting point of this product is right around ambient temperature at 18-20°C. Depending on the transportation considerations, the product may arrive as either.

      Helpful?

  6. Is Product 377996, Titanium (IV) isopropoxide packaged under an inert gas?

    1 answer
    1. Yes, we package this product under nitrogen. This product is considered air and moisture sensitive. The MSDS recommends handling and storing titanium (IV) isopropoxide under nitrogen.

      Helpful?

  7. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

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